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Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes

Complex geometries for electrodes are a great challenge in electrochemical applications. Slurry electrodes have been one example, which use complex flow distributors to improve the charge transfer between the current collector and the slurry particles. Here we use titanium‐based flow distributors pr...

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Autores principales: Percin, Korcan, Hereijgers, Jonas, Mulandi, Nicolas, Breugelmans, Tom, Wessling, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108113/
https://www.ncbi.nlm.nih.gov/pubmed/37082101
http://dx.doi.org/10.1002/celc.202200928
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author Percin, Korcan
Hereijgers, Jonas
Mulandi, Nicolas
Breugelmans, Tom
Wessling, Matthias
author_facet Percin, Korcan
Hereijgers, Jonas
Mulandi, Nicolas
Breugelmans, Tom
Wessling, Matthias
author_sort Percin, Korcan
collection PubMed
description Complex geometries for electrodes are a great challenge in electrochemical applications. Slurry electrodes have been one example, which use complex flow distributors to improve the charge transfer between the current collector and the slurry particles. Here we use titanium‐based flow distributors produced by indirect 3D‐printing to improve further the electron transfer from highly conductive flow distributors to the slurry particles for a vanadium redox flow application. The titanium static mixers are directly coated with graphite to increase the activity for vanadium redox reactions. Increasing layers of graphite have shown an optimum for the positive and negative electrolytes. The application of heat treatment on the electrodes improves the anodic and cathodic current peaks drastically. Testing the highly conductive static mixers in a self‐made redox flow cell results in 110 mA cm(−2) discharge polarization.
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spelling pubmed-101081132023-04-18 Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes Percin, Korcan Hereijgers, Jonas Mulandi, Nicolas Breugelmans, Tom Wessling, Matthias ChemElectroChem Research Articles Complex geometries for electrodes are a great challenge in electrochemical applications. Slurry electrodes have been one example, which use complex flow distributors to improve the charge transfer between the current collector and the slurry particles. Here we use titanium‐based flow distributors produced by indirect 3D‐printing to improve further the electron transfer from highly conductive flow distributors to the slurry particles for a vanadium redox flow application. The titanium static mixers are directly coated with graphite to increase the activity for vanadium redox reactions. Increasing layers of graphite have shown an optimum for the positive and negative electrolytes. The application of heat treatment on the electrodes improves the anodic and cathodic current peaks drastically. Testing the highly conductive static mixers in a self‐made redox flow cell results in 110 mA cm(−2) discharge polarization. John Wiley and Sons Inc. 2023-01-10 2023-02-01 /pmc/articles/PMC10108113/ /pubmed/37082101 http://dx.doi.org/10.1002/celc.202200928 Text en © 2023 The Authors. ChemElectroChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Percin, Korcan
Hereijgers, Jonas
Mulandi, Nicolas
Breugelmans, Tom
Wessling, Matthias
Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title_full Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title_fullStr Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title_full_unstemmed Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title_short Titanium‐Based Static Mixer Electrodes to Improve the Current Density of Slurry Electrodes
title_sort titanium‐based static mixer electrodes to improve the current density of slurry electrodes
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108113/
https://www.ncbi.nlm.nih.gov/pubmed/37082101
http://dx.doi.org/10.1002/celc.202200928
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