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Palladium(0)‐Catalyzed Anti‐Selective Addition‐Cyclizations of Alkynyl Electrophiles
Palladium(0)/monophosphine complexes catalyze anti‐selective alkylative, arylative, and alkynylative cyclizations of alkynyl electrophiles with organometallic reagents. The remarkable anti‐selectivity results from novel oxidative addition, that is, the nucleophilic attack of electron‐rich palladium(...
Autores principales: | Tsukamoto, Hirokazu, Ito, Kazuya, Ueno, Tatsuhiko, Shiraishi, Mitsugu, Kondo, Yoshinori, Doi, Takayuki |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108115/ https://www.ncbi.nlm.nih.gov/pubmed/36333971 http://dx.doi.org/10.1002/chem.202203068 |
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