Evidence of Sulfur Non‐Innocence in [Co(II)(dithiacyclam)](2+)‐Mediated Catalytic Oxygen Reduction Reactions

In many metalloenzymes, sulfur‐containing ligands participate in catalytic processes, mainly via the involvement in electron transfer reactions. In a biomimetic approach, we now demonstrate the implication of S‐ligation in cobalt mediated oxygen reduction reactions (ORR). A comparative study between...

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Detalles Bibliográficos
Autores principales: Battistella, Beatrice, Iffland‐Mühlhaus, Linda, Schütze, Maximillian, Cula, Beatrice, Kuhlmann, Uwe, Dau, Holger, Hildebrandt, Peter, Lohmiller, Thomas, Mebs, Stefan, Apfel, Ulf‐Peter, Ray, Kallol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108118/
https://www.ncbi.nlm.nih.gov/pubmed/36378951
http://dx.doi.org/10.1002/anie.202214074

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