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Askival: An altered feldspathic cumulate sample in Gale crater

Askival is a light‐toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi,...

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Autores principales: Bowden, Donald Lewis, Bridges, John C., Cousin, Agnes, Rapin, William, Semprich, Julia, Gasnault, Olivier, Forni, Olivier, Gasda, Patrick, Das, Debarati, Payré, Valerie, Sautter, Violaine, Bedford, Candice C., Wiens, Roger C., Pinet, Patrick, Frydenvang, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108227/
https://www.ncbi.nlm.nih.gov/pubmed/37082523
http://dx.doi.org/10.1111/maps.13933
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author Bowden, Donald Lewis
Bridges, John C.
Cousin, Agnes
Rapin, William
Semprich, Julia
Gasnault, Olivier
Forni, Olivier
Gasda, Patrick
Das, Debarati
Payré, Valerie
Sautter, Violaine
Bedford, Candice C.
Wiens, Roger C.
Pinet, Patrick
Frydenvang, Jens
author_facet Bowden, Donald Lewis
Bridges, John C.
Cousin, Agnes
Rapin, William
Semprich, Julia
Gasnault, Olivier
Forni, Olivier
Gasda, Patrick
Das, Debarati
Payré, Valerie
Sautter, Violaine
Bedford, Candice C.
Wiens, Roger C.
Pinet, Patrick
Frydenvang, Jens
author_sort Bowden, Donald Lewis
collection PubMed
description Askival is a light‐toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral‐alkaline pH. Through laser‐induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe‐Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg‐rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars.
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spelling pubmed-101082272023-04-18 Askival: An altered feldspathic cumulate sample in Gale crater Bowden, Donald Lewis Bridges, John C. Cousin, Agnes Rapin, William Semprich, Julia Gasnault, Olivier Forni, Olivier Gasda, Patrick Das, Debarati Payré, Valerie Sautter, Violaine Bedford, Candice C. Wiens, Roger C. Pinet, Patrick Frydenvang, Jens Meteorit Planet Sci Articles Askival is a light‐toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral‐alkaline pH. Through laser‐induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe‐Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg‐rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars. John Wiley and Sons Inc. 2022-12-04 2023-01 /pmc/articles/PMC10108227/ /pubmed/37082523 http://dx.doi.org/10.1111/maps.13933 Text en © 2022 The Authors. Meteoritics & Planetary Science published by Wiley Periodicals LLC on behalf of The Meteoritical Society. https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Articles
Bowden, Donald Lewis
Bridges, John C.
Cousin, Agnes
Rapin, William
Semprich, Julia
Gasnault, Olivier
Forni, Olivier
Gasda, Patrick
Das, Debarati
Payré, Valerie
Sautter, Violaine
Bedford, Candice C.
Wiens, Roger C.
Pinet, Patrick
Frydenvang, Jens
Askival: An altered feldspathic cumulate sample in Gale crater
title Askival: An altered feldspathic cumulate sample in Gale crater
title_full Askival: An altered feldspathic cumulate sample in Gale crater
title_fullStr Askival: An altered feldspathic cumulate sample in Gale crater
title_full_unstemmed Askival: An altered feldspathic cumulate sample in Gale crater
title_short Askival: An altered feldspathic cumulate sample in Gale crater
title_sort askival: an altered feldspathic cumulate sample in gale crater
topic Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108227/
https://www.ncbi.nlm.nih.gov/pubmed/37082523
http://dx.doi.org/10.1111/maps.13933
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