A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H(2)O(2) and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst

The mechanism and the reactive species involved in the oxidation of alkenes, and alcohols with H(2)O(2), catalysed by an in situ prepared mixture of a Mn(II) salt, pyridine‐2‐carboxylic acid and a ketone is elucidated using substrate competition experiments, kinetic isotope effect (KIE) measurements...

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Detalles Bibliográficos
Autores principales: Kasper, Johann B., Saisaha, Pattama, de Roo, Maurits, Groen, Mitchell J., Vicens, Laia, Borrell, Margarida, de Boer, Johannes W., Hage, Ronald, Costas, Miquel, Browne, Wesley R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108234/
https://www.ncbi.nlm.nih.gov/pubmed/37082112
http://dx.doi.org/10.1002/cctc.202201072

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