Wacker Oxidation of Methylenecyclobutanes: Scope and Selectivity in an Unusual Setting

Methylenecyclobutanes are found to undergo Wacker oxidation via a semi‐pinacol‐type rearrangement. Key to a successful process is the use of tert‐butyl nitrite as oxidant, which not only enables efficient catalyst turn‐over but also ensures high Markovnikov‐selectivity under mild conditions. Thus, c...

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Detalles Bibliográficos
Autores principales: Sietmann, Jan, Tenberge, Marius, Wahl, Johannes M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108300/
https://www.ncbi.nlm.nih.gov/pubmed/36416612
http://dx.doi.org/10.1002/anie.202215381

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108300/
https://www.ncbi.nlm.nih.gov/pubmed/36416612
http://dx.doi.org/10.1002/anie.202215381

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