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Wacker Oxidation of Methylenecyclobutanes: Scope and Selectivity in an Unusual Setting
Methylenecyclobutanes are found to undergo Wacker oxidation via a semi‐pinacol‐type rearrangement. Key to a successful process is the use of tert‐butyl nitrite as oxidant, which not only enables efficient catalyst turn‐over but also ensures high Markovnikov‐selectivity under mild conditions. Thus, c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108300/ https://www.ncbi.nlm.nih.gov/pubmed/36416612 http://dx.doi.org/10.1002/anie.202215381 |