Cargando…

A unified superatomic-molecule theory for local aromaticity in π-conjugated systems

Aromaticity is one of the most important concepts in chemistry. However, there is still no unified chemical insight for various systems with conjugated sp(2) carbon. Herein, we proposed a superatomic-molecule theory to build a generalized electron rule for polycyclic conjugated hydrocarbons, fullere...

Descripción completa

Detalles Bibliográficos
Autores principales:	Li, Dan, Yang, Jinlong, Cheng, Longjiu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Oxford University Press 2022
Materias:	Research Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10112841/ https://www.ncbi.nlm.nih.gov/pubmed/37081992 http://dx.doi.org/10.1093/nsr/nwac216

Ejemplares similares

Evidence for the Superatom–Superatom Bonding from Bond Energies
por: Zheng, Qijian, et al.
Publicado: (2018)

Assembling Au(4) Tetrahedra to 2D and 3D Superatomic Crystals Based on Superatomic-Network Model
por: Yan, Chen, et al.
Publicado: (2022)

Magnetically induced currents and aromaticity in ligand-stabilized Au and AuPt superatoms
por: López-Estrada, Omar, et al.
Publicado: (2021)

New Perspectives on the Electronic and Geometric Structure of Au(70)S(20)(PPh(3))(12) Cluster: Superatomic-Network Core Protected by Novel Au(12)(µ(3)-S)(10) Staple Motifs
por: Tian, Zhimei, et al.
Publicado: (2019)

Controlling the helicity of π-conjugated oligomers by tuning the aromatic backbone twist
por: Bedi, Anjan, et al.
Publicado: (2022)

The Effect of Aromatic Diimide Side Groups on the π-Conjugated Polymer Properties
por: Drewniak, Anna, et al.
Publicado: (2018)

Functional group introduction and aromatic unit variation in a set of π-conjugated macrocycles: revealing the central role of local and global aromaticity
por: Rimmele, Martina, et al.
Publicado: (2021)

Author Correction: Magnetically induced currents and aromaticity in ligand-stabilized Au and AuPt superatoms
por: López-Estrada, Omar, et al.
Publicado: (2022)

Aromatic-aromatic interactions: analysis of π-π interactions in interleukins and TNF proteins
por: Sivasakthi, Vaideeswaran, et al.
Publicado: (2013)

Superatomic states under high pressure
por: Wang, Rui, et al.
Publicado: (2023)

The behavior of the aluminum trimer when combining with different superatom clusters
por: Yang, Hui, et al.
Publicado: (2018)

The chiral phase transition, toponium and superatoms
por: Dremin, I M
Publicado: (1987)

Obtaining Intrinsically Occupied Free-Space Superatom States in an Encapsulated Ca(2)N Nanotube
por: Abbas, Ghulam, et al.
Publicado: (2018)

Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger π-conjugated naphthopyrans with aggregation-induced emission characters
por: Zhang, Jinlong, et al.
Publicado: (2018)

Three-Dimensional Fully π-Conjugated Macrocycles: When 3D-Aromatic and When 2D-Aromatic-in-3D?
por: El Bakouri, Ouissam, et al.
Publicado: (2022)

Efficient Colorimetric Fluoride Anion Sensor Based on π-Conjugated Carbazole Small Molecule
por: Deng, Zhifeng, et al.
Publicado: (2021)

Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes – a tool for estimating π-conjugation in aromatic systems
por: Janhsen, B., et al.
Publicado: (2017)

As Nice as π: Aromatic Reactions Activated by π‐Coordination to Transition Metals
por: Williams, Luke J., et al.
Publicado: (2021)

Dispersion Interactions in Exciton-Localized States. Theory and Applications to π–π* and n−π* Excited States
por: Jangrouei, Mohammad Reza, et al.
Publicado: (2022)

Portraits of Soot Molecules Reveal Pathways to Large Aromatics, Five-/Seven-Membered Rings, and Inception through π-Radical Localization
por: Lieske, Leonard-Alexander, et al.
Publicado: (2023)

Electrostatics does not dictate the slip-stacked arrangement of aromatic π–π interactions
por: Carter-Fenk, Kevin, et al.
Publicado: (2020)

Learning a Local-Variable Model of Aromatic and Conjugated Systems
por: Matlock, Matthew K., et al.
Publicado: (2018)

Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems
por: Chen, Shiyan, et al.
Publicado: (2020)

Two-Dimensional Nanosheets from Redox-Active Superatoms
por: Champsaur, Anouck M., et al.
Publicado: (2017)

Hydration of Aromatic Heterocycles as an Adversary of π-Stacking
por: Loeffler, Johannes R., et al.
Publicado: (2019)

π-Diradical Aromatic Soot Precursors in Flames
por: Martin, Jacob W., et al.
Publicado: (2021)

Nanoscale π-conjugated ladders
por: Meißner, Stefanie A., et al.
Publicado: (2021)

Nanoscale Crystalline Sheets and Vesicles Assembled from Nonplanar Cyclic π-Conjugated Molecules
por: Tang, Huang, et al.
Publicado: (2019)

Structure and Optical Bandgap Relationship of π-Conjugated Systems
por: Botelho, André Leitão, et al.
Publicado: (2014)

Extended-conjugation π-electron systems in carbon nanotubes
por: Miyaura, Kenshi, et al.
Publicado: (2018)

Surface modifications of eight-electron palladium silver superatomic alloys
por: Barik, Subrat Kumar, et al.
Publicado: (2022)

Superatomic icosahedral-C(n)B(12-n) (n = 0, 1, 2) Stuffed mononuclear and binuclear borafullerene and borospherene nanoclusters with spherical aromaticity
por: Zhang, Min, et al.
Publicado: (2022)

Forty years of Clar's aromatic π-sextet rule
por: Solà, Miquel
Publicado: (2013)

Searching for double σ- and π-aromaticity in borazine derivatives
por: Pino-Rios, Ricardo, et al.
Publicado: (2020)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings
por: Bloch, Jan, et al.
Publicado: (2020)

Fluoromaticity: The Molecular Orbital Contributions of Fluorine Substituents to the π-Systems of Aromatic Rings
por: Fuhrer, Timothy J., et al.
Publicado: (2021)

Novel Diketopyrrolopyrrole-Based π-Conjugated Molecules Synthesized Via One-Pot Direct Arylation Reaction
por: Liu, Hui, et al.
Publicado: (2019)

New Advances in π-Conjugated Materials
por: Miao, Chuanqi, et al.
Publicado: (2023)

Multifunctional π‐Conjugated Additives for Halide Perovskite
por: Lao, Yinan, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ap4crl5sl3gdpuvrssjdh0gvfe