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Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water

In this work, sulphur doped copper ferrites (S-CuFe(2)O(4)) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results r...

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Autores principales: Aslam, Anam, Abid, Muhammad Zeeshan, Rafiq, Khezina, Rauf, Abdul, Hussain, Ejaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10113332/
https://www.ncbi.nlm.nih.gov/pubmed/37072442
http://dx.doi.org/10.1038/s41598-023-33185-0
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author Aslam, Anam
Abid, Muhammad Zeeshan
Rafiq, Khezina
Rauf, Abdul
Hussain, Ejaz
author_facet Aslam, Anam
Abid, Muhammad Zeeshan
Rafiq, Khezina
Rauf, Abdul
Hussain, Ejaz
author_sort Aslam, Anam
collection PubMed
description In this work, sulphur doped copper ferrites (S-CuFe(2)O(4)) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe(2)O(4) nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe(2)O(4) over pristine CuFe(2)O(4). On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science.
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spelling pubmed-101133322023-04-20 Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water Aslam, Anam Abid, Muhammad Zeeshan Rafiq, Khezina Rauf, Abdul Hussain, Ejaz Sci Rep Article In this work, sulphur doped copper ferrites (S-CuFe(2)O(4)) photocatalysts were successfully synthesized for the first time using the facile hydrothermal method. The as-synthesized photocatalysts were characterized through XRD, Raman, TGA, FT-IR, UV–Vis-DRS, SEM, EDX and PL techniques. The results revealed that doping with sulphur has been found to be a suitable alternative that causes strain in the lattices as anions replace the oxygen from the CuFe(2)O(4) nanostructures. Due to sulphur dopants, photocatalysts are able to efficiently trap and transfer the photoinduced charges, which readily suppress charge recombination. A UV–Vis spectrophotometer was used to monitor the degradation of selective toxic organic dyes (RhB, CR, MO, and CV) in aqueous media. The dye degradation results provide evidence for the surprisingly superior performance of S-CuFe(2)O(4) over pristine CuFe(2)O(4). On the basis of its efficiencies, this work can be assigned as an excellent candidate for photocatalysis science. Nature Publishing Group UK 2023-04-18 /pmc/articles/PMC10113332/ /pubmed/37072442 http://dx.doi.org/10.1038/s41598-023-33185-0 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Aslam, Anam
Abid, Muhammad Zeeshan
Rafiq, Khezina
Rauf, Abdul
Hussain, Ejaz
Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title_full Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title_fullStr Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title_full_unstemmed Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title_short Tunable sulphur doping on CuFe(2)O(4) nanostructures for the selective elimination of organic dyes from water
title_sort tunable sulphur doping on cufe(2)o(4) nanostructures for the selective elimination of organic dyes from water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10113332/
https://www.ncbi.nlm.nih.gov/pubmed/37072442
http://dx.doi.org/10.1038/s41598-023-33185-0
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