Short-Term Effects: Elemental and Morphological Assessment of Aerosols Over Old Delhi Region, India

This study presents morphological and elemental characteristics of aerosols for the duration January-June, 2021, using Scanning Electron Microscope coupled with Energy Dispersive X-Ray (SEM–EDX). The results revealed that there were numerous spherical particles (D(α) ≤ 2.5 µm) but did not produced the expected EDX-spectra for elemental constituents. Limited deposited particles were observed which showed definite elemental constitutions. The results show that Cl, S, Al, Ca, K, Fe, Zn, Na, Mg, N, Tb, Ti, Ni, F, Cd, Cu, Mn, P and Cr were the overall determined elements, out of which Cl, S, Al, Ca, K, Fe, Zn, Na and Mg were the major constituents. Variation in particles’ shapes whether definite or irregular, columnar or spherical, flaky or aggregate or crystal-accumulation were attained on the basis of the major constituting element, majorly Ca-rich, S-rich, Cl-rich and Fe-rich. Interestingly, the physical characteristics of the particles varied with variation in elemental composition. All these indicate that there were specific sources contributing toward distinct particle-morphs. Ti, Tb and Cd need more analytical studies for their percent contribution. S, Cl and K contributed the most to the elemental composition as revealed by elemental relative proportion. Atomic weight percent curves for elements were slightly scattered during May. These probably played important role in defining the diversity indices, which was highest for April (2.17 ± 0.12). Particles containing six (P(6)) to nine (P(9)) elements dominated in this study, and particles containing seven elements (P(7)) were generally observed.