An organic cage controlling the dimension and stability of gold nanoparticles

A molecular cage encapsulating gold nanoparticles is presented. Six benzylic thioethers are pointing into its cavity, stabilizing the particles in a 1 : 1 ligand-to-particle-ratio in excellent yields. They are bench-stable for several months and can withstand unprecedented thermal stress of up to 13...

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Detalles Bibliográficos
Autores principales: Peters, Erich Henrik, Mayor, Marcel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116599/
https://www.ncbi.nlm.nih.gov/pubmed/37009693
http://dx.doi.org/10.1039/d3cc00277b
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author Peters, Erich Henrik
Mayor, Marcel
author_facet Peters, Erich Henrik
Mayor, Marcel
author_sort Peters, Erich Henrik
collection PubMed
description A molecular cage encapsulating gold nanoparticles is presented. Six benzylic thioethers are pointing into its cavity, stabilizing the particles in a 1 : 1 ligand-to-particle-ratio in excellent yields. They are bench-stable for several months and can withstand unprecedented thermal stress of up to 130 °C, documenting the advantages of the cage-type stabilization over open-chain analogues.
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spelling pubmed-101165992023-04-21 An organic cage controlling the dimension and stability of gold nanoparticles Peters, Erich Henrik Mayor, Marcel Chem Commun (Camb) Chemistry A molecular cage encapsulating gold nanoparticles is presented. Six benzylic thioethers are pointing into its cavity, stabilizing the particles in a 1 : 1 ligand-to-particle-ratio in excellent yields. They are bench-stable for several months and can withstand unprecedented thermal stress of up to 130 °C, documenting the advantages of the cage-type stabilization over open-chain analogues. The Royal Society of Chemistry 2023-03-24 /pmc/articles/PMC10116599/ /pubmed/37009693 http://dx.doi.org/10.1039/d3cc00277b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Peters, Erich Henrik
Mayor, Marcel
An organic cage controlling the dimension and stability of gold nanoparticles
title An organic cage controlling the dimension and stability of gold nanoparticles
title_full An organic cage controlling the dimension and stability of gold nanoparticles
title_fullStr An organic cage controlling the dimension and stability of gold nanoparticles
title_full_unstemmed An organic cage controlling the dimension and stability of gold nanoparticles
title_short An organic cage controlling the dimension and stability of gold nanoparticles
title_sort organic cage controlling the dimension and stability of gold nanoparticles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116599/
https://www.ncbi.nlm.nih.gov/pubmed/37009693
http://dx.doi.org/10.1039/d3cc00277b
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