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The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance

[Image: see text] Water-based superamphiphobic coatings are environment-friendly, which have attracted tremendous attention recently, but the performances are severely limited by the dispersibility of hydrophobic particles. To solve the poor dispersibility of modified silica powder with hydrophobici...

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Autores principales: Ren, Guoyu, Qiao, Zeting, Hui, Zhi, Tuo, Yun, Zheng, Wenjie, Chen, Xiaodong, Li, Shiying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116617/
https://www.ncbi.nlm.nih.gov/pubmed/37091376
http://dx.doi.org/10.1021/acsomega.2c06859
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author Ren, Guoyu
Qiao, Zeting
Hui, Zhi
Tuo, Yun
Zheng, Wenjie
Chen, Xiaodong
Li, Shiying
author_facet Ren, Guoyu
Qiao, Zeting
Hui, Zhi
Tuo, Yun
Zheng, Wenjie
Chen, Xiaodong
Li, Shiying
author_sort Ren, Guoyu
collection PubMed
description [Image: see text] Water-based superamphiphobic coatings are environment-friendly, which have attracted tremendous attention recently, but the performances are severely limited by the dispersibility of hydrophobic particles. To solve the poor dispersibility of modified silica powder with hydrophobicity, silica dispersion was blended with polytetrafluoroethylene (PTFE) emulsion and modified aluminum tripolyphosphate (ATP) dispersion to successfully prepare water-based coatings. Multifunctional coatings were prepared by one-step spraying. It possessed good adhesion (grade 1), excellent antifouling, impact resistance, chemical stability (acid and alkali resistance for 96 h of immersion), and corrosion resistance (3.5 wt % NaCl solutions for 20 days). More importantly, the superamphiphobic coatings had high contact angles (CAs) and low slide angles (SAs) for ethylene glycol (CAs = 154 ± 0.8°; SAs = 13 ± 0.7°) and water (CAs = 158 ± 0.7°; SAs = 4 ± 0.3°). Furthermore, the composite coating was still hydrophobic after 35 cycles of wear with high roughness sandpaper (120 mesh) under three different loads, which maintained superamphiphobicity at 425 °C. This work is expected to provide a facile idea and method for the preparation of waterborne superamphiphobic coatings.
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spelling pubmed-101166172023-04-21 The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance Ren, Guoyu Qiao, Zeting Hui, Zhi Tuo, Yun Zheng, Wenjie Chen, Xiaodong Li, Shiying ACS Omega [Image: see text] Water-based superamphiphobic coatings are environment-friendly, which have attracted tremendous attention recently, but the performances are severely limited by the dispersibility of hydrophobic particles. To solve the poor dispersibility of modified silica powder with hydrophobicity, silica dispersion was blended with polytetrafluoroethylene (PTFE) emulsion and modified aluminum tripolyphosphate (ATP) dispersion to successfully prepare water-based coatings. Multifunctional coatings were prepared by one-step spraying. It possessed good adhesion (grade 1), excellent antifouling, impact resistance, chemical stability (acid and alkali resistance for 96 h of immersion), and corrosion resistance (3.5 wt % NaCl solutions for 20 days). More importantly, the superamphiphobic coatings had high contact angles (CAs) and low slide angles (SAs) for ethylene glycol (CAs = 154 ± 0.8°; SAs = 13 ± 0.7°) and water (CAs = 158 ± 0.7°; SAs = 4 ± 0.3°). Furthermore, the composite coating was still hydrophobic after 35 cycles of wear with high roughness sandpaper (120 mesh) under three different loads, which maintained superamphiphobicity at 425 °C. This work is expected to provide a facile idea and method for the preparation of waterborne superamphiphobic coatings. American Chemical Society 2023-04-04 /pmc/articles/PMC10116617/ /pubmed/37091376 http://dx.doi.org/10.1021/acsomega.2c06859 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ren, Guoyu
Qiao, Zeting
Hui, Zhi
Tuo, Yun
Zheng, Wenjie
Chen, Xiaodong
Li, Shiying
The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title_full The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title_fullStr The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title_full_unstemmed The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title_short The Waterborne Superamphiphobic Coatings with Antifouling, High Temperature Resistance, and Corrosion Resistance
title_sort waterborne superamphiphobic coatings with antifouling, high temperature resistance, and corrosion resistance
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116617/
https://www.ncbi.nlm.nih.gov/pubmed/37091376
http://dx.doi.org/10.1021/acsomega.2c06859
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