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Chiral Polaritonics: Analytical Solutions, Intuition, and Use
[Image: see text] Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical react...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10123817/ https://www.ncbi.nlm.nih.gov/pubmed/37052302 http://dx.doi.org/10.1021/acs.jpclett.3c00286 |
Sumario: | [Image: see text] Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical reactivity, the latter requiring strong coupling. In this work, we derive an analytical solution to a system of many chiral emitters interacting with a chiral cavity similar to the widely used Tavis–Cummings and Hopfield models of quantum optics. We are able to estimate the discriminating strength of chiral polaritonics, discuss possible future development directions and exciting applications such as elucidating homochirality, and deliver much needed intuition to foster the newly flourishing field of chiral polaritonics. |
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