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Chiral Polaritonics: Analytical Solutions, Intuition, and Use

[Image: see text] Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical react...

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Autores principales: Schäfer, Christian, Baranov, Denis G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10123817/
https://www.ncbi.nlm.nih.gov/pubmed/37052302
http://dx.doi.org/10.1021/acs.jpclett.3c00286
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author Schäfer, Christian
Baranov, Denis G.
author_facet Schäfer, Christian
Baranov, Denis G.
author_sort Schäfer, Christian
collection PubMed
description [Image: see text] Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical reactivity, the latter requiring strong coupling. In this work, we derive an analytical solution to a system of many chiral emitters interacting with a chiral cavity similar to the widely used Tavis–Cummings and Hopfield models of quantum optics. We are able to estimate the discriminating strength of chiral polaritonics, discuss possible future development directions and exciting applications such as elucidating homochirality, and deliver much needed intuition to foster the newly flourishing field of chiral polaritonics.
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spelling pubmed-101238172023-04-25 Chiral Polaritonics: Analytical Solutions, Intuition, and Use Schäfer, Christian Baranov, Denis G. J Phys Chem Lett [Image: see text] Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical reactivity, the latter requiring strong coupling. In this work, we derive an analytical solution to a system of many chiral emitters interacting with a chiral cavity similar to the widely used Tavis–Cummings and Hopfield models of quantum optics. We are able to estimate the discriminating strength of chiral polaritonics, discuss possible future development directions and exciting applications such as elucidating homochirality, and deliver much needed intuition to foster the newly flourishing field of chiral polaritonics. American Chemical Society 2023-04-13 /pmc/articles/PMC10123817/ /pubmed/37052302 http://dx.doi.org/10.1021/acs.jpclett.3c00286 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Schäfer, Christian
Baranov, Denis G.
Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title_full Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title_fullStr Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title_full_unstemmed Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title_short Chiral Polaritonics: Analytical Solutions, Intuition, and Use
title_sort chiral polaritonics: analytical solutions, intuition, and use
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10123817/
https://www.ncbi.nlm.nih.gov/pubmed/37052302
http://dx.doi.org/10.1021/acs.jpclett.3c00286
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