T-type cell mediated photoacoustic spectroscopy for simultaneous detection of multi-component gases based on triple resonance modality

Enhancing multi-gas detectability using photoacoustic spectroscopy capable of simultaneous detection, highly selectivity and less cross-interference is essential for dissolved gas sensing application. A T-type photoacoustic cell was designed and verified to be an appropriate sensor, due to the resonant frequencies of which are determined jointly by absorption and resonant cylinders. The three designated resonance modes were investigated from both simulation and experiments to present the comparable amplitude responses by introducing excitation beam position optimization. The capability of multi-gas detection was demonstrated by measuring CO, CH(4) and C(2)H(2) simultaneously using QCL, ICL and DFB lasers as excitation sources respectively. The influence of potential cross-sensitivity towards humidity have been examined in terms of multi-gas detection. The experimentally determined minimum detection limits of CO, CH(4) and C(2)H(2) were 89ppb, 80ppb and 664ppb respectively, corresponding to the normalized noise equivalent absorption coefficients of 5.75 × 10(−7) cm(−1) W Hz(−1/2), 1.97 × 10(−8) cm(−1) W Hz(−1/2) and 4.23 × 10(−8) cm(−1) W Hz(−1/2).