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Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)

[Image: see text] Ruthenium catalysts bearing cyclic (alkyl)(amino)carbene (CAAC) ligands can attain very high productivities in olefin metathesis, owing to their resistance to unimolecular decomposition. Because the propagating methylidene species RuCl(2)(CAAC)(=CH(2)) is extremely susceptible to b...

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Detalles Bibliográficos
Autores principales:	Ou, Xinrui, Occhipinti, Giovanni, Boisvert, Eliza-Jayne Y., Jensen, Vidar R., Fogg, Deryn E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127214/ https://www.ncbi.nlm.nih.gov/pubmed/37123599 http://dx.doi.org/10.1021/acscatal.2c03828

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