Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand

The synthesis and solid-state characterisation of the heterobimetallic rhodium(iii)/silver(i) complex [Rh(2,2′-biphenyl)(CxP(2))Cl]⊃Ag(+) is described, where CxP(2) is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of...

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Detalles Bibliográficos
Autores principales: Emerson-King, Jack, Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127224/
https://www.ncbi.nlm.nih.gov/pubmed/37066625
http://dx.doi.org/10.1039/d3dt00567d
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author Emerson-King, Jack
Chaplin, Adrian B.
author_facet Emerson-King, Jack
Chaplin, Adrian B.
author_sort Emerson-King, Jack
collection PubMed
description The synthesis and solid-state characterisation of the heterobimetallic rhodium(iii)/silver(i) complex [Rh(2,2′-biphenyl)(CxP(2))Cl]⊃Ag(+) is described, where CxP(2) is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle.
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spelling pubmed-101272242023-04-26 Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand Emerson-King, Jack Chaplin, Adrian B. Dalton Trans Chemistry The synthesis and solid-state characterisation of the heterobimetallic rhodium(iii)/silver(i) complex [Rh(2,2′-biphenyl)(CxP(2))Cl]⊃Ag(+) is described, where CxP(2) is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle. The Royal Society of Chemistry 2023-04-03 /pmc/articles/PMC10127224/ /pubmed/37066625 http://dx.doi.org/10.1039/d3dt00567d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Emerson-King, Jack
Chaplin, Adrian B.
Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title_full Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title_fullStr Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title_full_unstemmed Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title_short Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
title_sort template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127224/
https://www.ncbi.nlm.nih.gov/pubmed/37066625
http://dx.doi.org/10.1039/d3dt00567d
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