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A Non-Hydrolytic Sol–Gel Route to Organic-Inorganic Hybrid Polymers: Linearly Expanded Silica and Silsesquioxanes
Condensation reactions of chlorosilanes (SiCl(4) and CH(3)SiCl(3)) and bis(trimethylsilyl)ethers of rigid, quasi-linear diols (CH(3))(3)SiO–AR–OSi(CH(3))(3) (AR = 4,4′-biphenylene (1) and 2,6-naphthylene (2)), with release of (CH(3))(3)SiCl as a volatile byproduct, afforded novel hybrid materials th...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10138140/ https://www.ncbi.nlm.nih.gov/pubmed/37102903 http://dx.doi.org/10.3390/gels9040291 |