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In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants

A new heterojunction material BP/RP-g-C(3)N(4)/SiO(2) was obtained by a one-step ball milling method, and its photocatalytic capacity was researched by the degradation of Rhodamine B (RhB) and ofloxacin (OFL) in simulated sunlight. The construction of an in situ BP/RP heterojunction can achieve perf...

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Autores principales: Li, Jiancheng, Wang, Chi, Ma, Yixing, Li, Kai, Mei, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10140671/
https://www.ncbi.nlm.nih.gov/pubmed/37124021
http://dx.doi.org/10.1039/d3ra01850d
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author Li, Jiancheng
Wang, Chi
Ma, Yixing
Li, Kai
Mei, Yi
author_facet Li, Jiancheng
Wang, Chi
Ma, Yixing
Li, Kai
Mei, Yi
author_sort Li, Jiancheng
collection PubMed
description A new heterojunction material BP/RP-g-C(3)N(4)/SiO(2) was obtained by a one-step ball milling method, and its photocatalytic capacity was researched by the degradation of Rhodamine B (RhB) and ofloxacin (OFL) in simulated sunlight. The construction of an in situ BP/RP heterojunction can achieve perfect interface contact between different semiconductors and effectively promote the separation of photogenerated carriers. The composite material was well characterized, which proved that the multi-heterogeneous structure was prepared. Furthermore, the type II heterojunction was formed between the g-C(3)N(4) and BP/RP interface, playing an important role in the degradation and promoting electron transfer. The degradation effect of BP/RP-g-C(3)N(4)/SiO(2) on RhB reached 90% after 26 min of simulated solar irradiation, which was 1.8 times that of g-C(3)N(4)/SiO(2). The degradation of OFL by BP/RP-g-C(3)N(4)/SiO(2) reached 85.3% after illumination for 50 min, while the degradation of g-C(3)N(4)/SiO(2) was only 35.4%. The mechanisms were further discussed, and ˙O(2)(−) and h(+) were found to be the main active substances to degrade RhB. The catalyst also revealed distinguished stability of catalyst and recyclability, and the degradation effect of RhB can still realize 85% after 4 runs of experiment. Thus, this study provided a novel method for the design and preparation of multi-heterojunction catalysts in the removal of organic pollutants from wastewater.
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spelling pubmed-101406712023-04-29 In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants Li, Jiancheng Wang, Chi Ma, Yixing Li, Kai Mei, Yi RSC Adv Chemistry A new heterojunction material BP/RP-g-C(3)N(4)/SiO(2) was obtained by a one-step ball milling method, and its photocatalytic capacity was researched by the degradation of Rhodamine B (RhB) and ofloxacin (OFL) in simulated sunlight. The construction of an in situ BP/RP heterojunction can achieve perfect interface contact between different semiconductors and effectively promote the separation of photogenerated carriers. The composite material was well characterized, which proved that the multi-heterogeneous structure was prepared. Furthermore, the type II heterojunction was formed between the g-C(3)N(4) and BP/RP interface, playing an important role in the degradation and promoting electron transfer. The degradation effect of BP/RP-g-C(3)N(4)/SiO(2) on RhB reached 90% after 26 min of simulated solar irradiation, which was 1.8 times that of g-C(3)N(4)/SiO(2). The degradation of OFL by BP/RP-g-C(3)N(4)/SiO(2) reached 85.3% after illumination for 50 min, while the degradation of g-C(3)N(4)/SiO(2) was only 35.4%. The mechanisms were further discussed, and ˙O(2)(−) and h(+) were found to be the main active substances to degrade RhB. The catalyst also revealed distinguished stability of catalyst and recyclability, and the degradation effect of RhB can still realize 85% after 4 runs of experiment. Thus, this study provided a novel method for the design and preparation of multi-heterojunction catalysts in the removal of organic pollutants from wastewater. The Royal Society of Chemistry 2023-04-28 /pmc/articles/PMC10140671/ /pubmed/37124021 http://dx.doi.org/10.1039/d3ra01850d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Jiancheng
Wang, Chi
Ma, Yixing
Li, Kai
Mei, Yi
In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title_full In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title_fullStr In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title_full_unstemmed In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title_short In situ formation of red/black phosphorus-modified SiO(2)@g-C(3)N(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
title_sort in situ formation of red/black phosphorus-modified sio(2)@g-c(3)n(4) multi-heterojunction for the enhanced photocatalytic degradation of organic contaminants
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10140671/
https://www.ncbi.nlm.nih.gov/pubmed/37124021
http://dx.doi.org/10.1039/d3ra01850d
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