Cargando…

Synthesis of Non-Aromatic Pyrroles Based on the Reaction of Carbonyl Derivatives of Acetylene with 3,3-Diaminoacrylonitriles

The reaction of 3,3-diaminoacrylonitriles with DMAD and 1,2-dibenzoylacetylene was studied. It is shown that the direction of the reaction depends on the structure both of acetylene and of diaminoacrylonitrile. In the reaction of DMAD with acrylonitriles bearing a monosubstituted amidine group, 1-su...

Descripción completa

Detalles Bibliográficos
Autores principales:	Silaichev, Pavel S., Dianova, Lidia N., Beryozkina, Tetyana V., Berseneva, Vera S., Maslivets, Andrey N., Bakulev, Vasiliy A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141133/ https://www.ncbi.nlm.nih.gov/pubmed/37110809 http://dx.doi.org/10.3390/molecules28083576

Ejemplares similares

Regioselective synthesis of heterocyclic N-sulfonyl amidines from heteroaromatic thioamides and sulfonyl azides
por: Ilkin, Vladimir, et al.
Publicado: (2020)

Spiroheterocyclization of Methyl 1-Aryl-3-cinnamoyl-4,5-dioxo-4,5-dihydro-1H-pyrrole-2-carboxylates by the Action of 3-(Arylamino)-1H-inden-1-ones
por: Silaichev, Pavel S., et al.
Publicado: (2012)

Selective Synthesis of Azoloyl NH-1,2,3-Triazoles and Azolyl Diazoketones: Experimental and Computational Insights
por: Shafran, Yuri M., et al.
Publicado: (2022)

Cyanothioacetamides as a synthetic platform for the synthesis of aminopyrazole derivatives
por: Filimonov, Valeriy O, et al.
Publicado: (2023)

Annulation of 1H-pyrrole-2,3-diones by thioacetamide: an approach to 5-azaisatins
por: Kobelev, Aleksandr I, et al.
Publicado: (2019)

Facile regiodivergent synthesis of spiro pyrrole-substituted pseudothiohydantoins and thiohydantoins via reaction of [e]-fused 1H-pyrrole-2,3-diones with thiourea
por: Kobelev, Aleksandr I, et al.
Publicado: (2019)

A facile approach to spiro[dihydrofuran-2,3'-oxindoles] via formal [4 + 1] annulation reaction of fused 1H-pyrrole-2,3-diones with diazooxindoles
por: Topanov, Pavel A, et al.
Publicado: (2022)

Cycloaddition of 4-Acyl-1H-pyrrole-2,3-diones Fused at [e]-Side and Cyanamides: Divergent Approach to 4H-1,3-Oxazines
por: Khramtsova, Ekaterina E., et al.
Publicado: (2022)

Amination of 5-Spiro-Substituted 3-Hydroxy-1,5-dihydro-2H-pyrrol-2-ones
por: Khramtsova, Ekaterina E., et al.
Publicado: (2021)

3,3′-Carbonyldipyridinium bis(perchlorate)
por: Zhang, Ya, et al.
Publicado: (2012)

Cycloaddition of Huisgen 1,4-dipoles: synthesis and rapid epimerization of functionalized spiropyrido[2,1-b][1,3]oxazine-pyrroles and related products
por: Galeev, Andrew R., et al.
Publicado: (2021)

Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2,3-diones with cyclic ketazinones en route to spirocyclic scaffolds
por: Dubovtsev, Alexey Yu, et al.
Publicado: (2017)

Combustion Products of Calcium Carbide Reused by Cu-Based Catalysts for Acetylene Carbonylation
por: Sun, Yongkang, et al.
Publicado: (2020)

Trapping evidence for the thermal cyclization of di-(o-acetylphenyl)acetylene to 3,3'-dimethyl-1,1'-biisobenzofuran
por: Casey, Charles P, et al.
Publicado: (2005)

Combined experimental and theoretical studies of regio- and stereoselectivity in reactions of β-isoxazolyl- and β-imidazolyl enamines with nitrile oxides
por: Efimov, Ilya V, et al.
Publicado: (2016)

One-Pot Metal-Free Synthesis of 3-CF(3)-1,3-Oxazinopyridines by Reaction of Pyridines with CF(3)CO-Acetylenes
por: Muzalevskiy, Vasiliy M., et al.
Publicado: (2019)

AlBr(3)-Promoted stereoselective anti-hydroarylation of the acetylene bond in 3-arylpropynenitriles by electron-rich arenes: synthesis of 3,3-diarylpropenenitriles
por: Gorbunova, Yelizaveta, et al.
Publicado: (2021)

Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
por: Kim, Hee-Joon
Publicado: (2010)

Crystal structure of ethyl 3-(4-chlorophenyl)-5-[(E)-2-(dimethylamino)ethenyl]-1,2-oxazole-4-carboxylate
por: Efimov, Ilya, et al.
Publicado: (2015)

2-[(1-Methyl-1H-pyrrol-2-yl)carbonylmethyl]isoindoline-1,3-dione
por: Schlosser, Joachim, et al.
Publicado: (2009)

Tailoring the pore chemistry in porous aromatic frameworks for selective separation of acetylene from ethylene
por: Zhou, Shuang, et al.
Publicado: (2022)

(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate
por: Yin, Shaohong, et al.
Publicado: (2009)

Carbonyl-assisted reverse regioselective cascade annulation of 2-acetylenic ketones triggered by Ru-catalyzed C–H activation
por: Gollapelli, Krishna Kumar, et al.
Publicado: (2016)

Bifunctional Fluorophosphonium Triflates as Intramolecular Frustrated Lewis Pairs: Reversible CO(2) Sequestration and Binding of Carbonyls, Nitriles and Acetylenes
por: Guo, Chun‐Xiang, et al.
Publicado: (2021)

Dibenzyl 3,3′,4,4′-tetramethyl-5,5′-(ethynediyl)bis(pyrrole-2-carboxylate)
por: Tanui, Hillary K., et al.
Publicado: (2007)

Synthesis of 1,4-benzothiazinones from acylpyruvic acids or furan-2,3-diones and o-aminothiophenol
por: Stepanova, Ekaterina E, et al.
Publicado: (2020)

The carbonyl-lock mechanism underlying non-aromatic fluorescence in biological matter
por: Mirón, Gonzalo Díaz, et al.
Publicado: (2023)

Carbon nitride photocatalyzes regioselective aminium radical addition to the carbonyl bond and yields N-fused pyrroles
por: Kurpil, Bogdan, et al.
Publicado: (2019)

Naphthalene diimide bis-guanidinio-carbonyl-pyrrole as a pH-switchable threading DNA intercalator
por: Jana, Poulami, et al.
Publicado: (2020)

Synthesis of Aromatic Rings Embedded in Polycyclic Scaffolds by Triyne Cycloaddition: Competition between Carbonylative and Non-Carbonylative Pathways
por: Salacz, Laura, et al.
Publicado: (2019)

Crystal structure and Hirshfeld surface analysis of dibutyl 5,5′-(pentane-3,3-diyl)bis(1H-pyrrole-5-carboxylate)
por: Wang, Haijing, et al.
Publicado: (2019)

Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene
por: Vidovič, Carina, et al.
Publicado: (2019)

Synthesis and Characterization of Novel D-A Type Neutral Blue Electrochromic Polymers Containing Pyrrole[3-c]Pyrrole-1,4-Diketone as the Acceptor Units and the Aromatics Donor Units with Different Planar Structures
por: Yue, Haoguo, et al.
Publicado: (2019)

1-[3-({[Bis(2-methylpropyl)carbamothioyl]amino}carbonyl)benzoyl]-3,3-bis(2-methylpropyl)thiourea
por: Selvakumaran, N., et al.
Publicado: (2013)

Dimethyl 3,3′-diphenyl-2,2′-[(S)-thiophene-2,5-diylbis(carbonylazanediyl)]dipropanoate
por: Xia, Guang-Ming, et al.
Publicado: (2010)

Differentiation between Isomeric 4,5-Functionalized 1,2,3-Thiadiazoles and 1,2,3-Triazoles by ESI-HRMS and IR Ion Spectroscopy
por: Mazur, Dmitrii M., et al.
Publicado: (2023)

Isosterism in pyrrole via azaboroles substitution, a theoretical investigation for electronic structural, stability and aromaticity
por: H. El-Demerdash, Safinaz, et al.
Publicado: (2023)

Electrogenerated poly(pyrrole-lactosyl) and poly(pyrrole-3'-sialyllactosyl) interfaces: toward the impedimetric detection of lectins
por: Gondran, Chantal, et al.
Publicado: (2013)

Palladium-catalyzed α-arylation of carbonyls in the de novo synthesis of aromatic heterocycles
por: Potukuchi, Harish K., et al.
Publicado: (2015)

1,3-Dipolar Cycloaddition Reactions of Substituted Benzyl Azides with Acetylenic Compounds
por: Abu-Orabi, Sultan T.
Publicado: (2002)

Cannot write session to /tmp/vufind_sessions/sess_qo5mlefm33naac8jkrbieco60q