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Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications

[Image: see text] Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundam...

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Autores principales: Hu, Peng, Hu, Ping, Vu, Tuan Duc, Li, Ming, Wang, Shancheng, Ke, Yujie, Zeng, Xianting, Mai, Liqiang, Long, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141335/
https://www.ncbi.nlm.nih.gov/pubmed/36972332
http://dx.doi.org/10.1021/acs.chemrev.2c00546
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author Hu, Peng
Hu, Ping
Vu, Tuan Duc
Li, Ming
Wang, Shancheng
Ke, Yujie
Zeng, Xianting
Mai, Liqiang
Long, Yi
author_facet Hu, Peng
Hu, Ping
Vu, Tuan Duc
Li, Ming
Wang, Shancheng
Ke, Yujie
Zeng, Xianting
Mai, Liqiang
Long, Yi
author_sort Hu, Peng
collection PubMed
description [Image: see text] Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V(2)O(3), V(3)O(5), VO(2), V(3)O(7), V(2)O(5), V(2)O(2), V(6)O(13), and V(4)O(9). We begin with a tutorial on the phase diagram of the V–O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications.
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spelling pubmed-101413352023-04-29 Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications Hu, Peng Hu, Ping Vu, Tuan Duc Li, Ming Wang, Shancheng Ke, Yujie Zeng, Xianting Mai, Liqiang Long, Yi Chem Rev [Image: see text] Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V(2)O(3), V(3)O(5), VO(2), V(3)O(7), V(2)O(5), V(2)O(2), V(6)O(13), and V(4)O(9). We begin with a tutorial on the phase diagram of the V–O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications. American Chemical Society 2023-03-27 /pmc/articles/PMC10141335/ /pubmed/36972332 http://dx.doi.org/10.1021/acs.chemrev.2c00546 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Hu, Peng
Hu, Ping
Vu, Tuan Duc
Li, Ming
Wang, Shancheng
Ke, Yujie
Zeng, Xianting
Mai, Liqiang
Long, Yi
Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title_full Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title_fullStr Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title_full_unstemmed Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title_short Vanadium Oxide: Phase Diagrams, Structures, Synthesis, and Applications
title_sort vanadium oxide: phase diagrams, structures, synthesis, and applications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141335/
https://www.ncbi.nlm.nih.gov/pubmed/36972332
http://dx.doi.org/10.1021/acs.chemrev.2c00546
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