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A Trinuclear Gadolinium Cluster with a Three-Center One-Electron Bond and an S = 11 Ground State
[Image: see text] The recent discovery of metal–metal bonding and valence delocalization in the dilanthanide complexes (Cp(iPr5))(2)Ln(2)I(3) (Cp(iPr5) = pentaisopropylcyclopentadienyl; Ln = Y, Gd, Tb, Dy) opened up the prospect of harnessing the 4f(n)5d(z(2))(1) electron configurations of non-tradi...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141408/ https://www.ncbi.nlm.nih.gov/pubmed/37068040 http://dx.doi.org/10.1021/jacs.3c00182 |