Electrical Conductance Mechanism of Silver–Polyacrylonitrile Nanocomposite Fibers

This paper presents the mechanism of electrical conductivity in nanocomposite polyacrylonitrile (PAN) fibers modified with silver nanoparticles (AgNPs). Fibers were formed by the wet-spinning method. The nanoparticles were introduced into the polymer matrix as a result of direct synthesis in the spinning solution from which the fibers were obtained, thereby influencing the chemical and physical properties of the polymer matrix. The structure of the nanocomposite fibers was determined using SEM, TEM, and XRD, and the electrical properties were determined using the DC and AC methods. The conductivity of the fibers was electronic and based on the percolation theory with tunneling through the polymer phase. This article describes in detail the influence of individual fiber parameters on the final electrical conductivity of the PAN/AgNPs composite and presents the mechanism of conductivity.