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Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance
To promote the anticorrosion performance of epoxy/zinc (EP/Zn) coating, graphene oxide (GO) was directly incorporated into dual-component paint. Interestingly, it was found that the method of incorporating GO during the fabrication of the composite paints strongly influenced their performance. The s...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10146711/ https://www.ncbi.nlm.nih.gov/pubmed/37112020 http://dx.doi.org/10.3390/polym15081873 |
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author | He, Shengjun Wei, Guangxiong Zhang, Zhengnan Yang, Lifeng Lin, Yuebin Du, Longji Du, Xusheng |
author_facet | He, Shengjun Wei, Guangxiong Zhang, Zhengnan Yang, Lifeng Lin, Yuebin Du, Longji Du, Xusheng |
author_sort | He, Shengjun |
collection | PubMed |
description | To promote the anticorrosion performance of epoxy/zinc (EP/Zn) coating, graphene oxide (GO) was directly incorporated into dual-component paint. Interestingly, it was found that the method of incorporating GO during the fabrication of the composite paints strongly influenced their performance. The samples were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and Raman spectroscopy. The results indicated that GO could be intercalated and modified with the polyamide curing agent while preparing component B of the paint, for which the interlayer spacing of the resulting polyamide modified GO (PGO) increased, and its dispersion in organic solvent was improved. The corrosion resistance of the coatings was studied through potentiodynamic polarization testing, electrochemical impedance spectroscopy (EIS), and immersion testing. Among the three types of as-prepared coatings, i.e., neat EP/Zn coating, GO modified EP/Zn coating (GO/EP/Zn), and PGO-modified EP/Zn coating (PGO/EP/Zn), the order of the corrosion resistance of the coatings was PGO/EP/Zn > GO/EP/Zn > neat EP/Zn. This work demonstrates that although the in situ modification of GO with a curing agent is a simple method, it evidently promotes the shielding effect of the coating and enhances its corrosion resistance. |
format | Online Article Text |
id | pubmed-10146711 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-101467112023-04-29 Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance He, Shengjun Wei, Guangxiong Zhang, Zhengnan Yang, Lifeng Lin, Yuebin Du, Longji Du, Xusheng Polymers (Basel) Article To promote the anticorrosion performance of epoxy/zinc (EP/Zn) coating, graphene oxide (GO) was directly incorporated into dual-component paint. Interestingly, it was found that the method of incorporating GO during the fabrication of the composite paints strongly influenced their performance. The samples were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and Raman spectroscopy. The results indicated that GO could be intercalated and modified with the polyamide curing agent while preparing component B of the paint, for which the interlayer spacing of the resulting polyamide modified GO (PGO) increased, and its dispersion in organic solvent was improved. The corrosion resistance of the coatings was studied through potentiodynamic polarization testing, electrochemical impedance spectroscopy (EIS), and immersion testing. Among the three types of as-prepared coatings, i.e., neat EP/Zn coating, GO modified EP/Zn coating (GO/EP/Zn), and PGO-modified EP/Zn coating (PGO/EP/Zn), the order of the corrosion resistance of the coatings was PGO/EP/Zn > GO/EP/Zn > neat EP/Zn. This work demonstrates that although the in situ modification of GO with a curing agent is a simple method, it evidently promotes the shielding effect of the coating and enhances its corrosion resistance. MDPI 2023-04-13 /pmc/articles/PMC10146711/ /pubmed/37112020 http://dx.doi.org/10.3390/polym15081873 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article He, Shengjun Wei, Guangxiong Zhang, Zhengnan Yang, Lifeng Lin, Yuebin Du, Longji Du, Xusheng Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title | Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title_full | Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title_fullStr | Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title_full_unstemmed | Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title_short | Incorporation of Graphene Oxide Modified with Polyamide Curing Agent into the Epoxy–Zinc Composite Coating for Promoting Its Corrosion Resistance |
title_sort | incorporation of graphene oxide modified with polyamide curing agent into the epoxy–zinc composite coating for promoting its corrosion resistance |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10146711/ https://www.ncbi.nlm.nih.gov/pubmed/37112020 http://dx.doi.org/10.3390/polym15081873 |
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