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Cinchona alkaloids – acid, anion-driven fluorescent INHIBIT logic gates with a receptor(1)–fluorophore–spacer–receptor(2) format and PET and ICT mechanisms

The fluorescent natural products, quinine, quinidine, cinchonine and cinchonidine are demonstrated as H(+)-enabled, halide-disabled (Cl(−), Br(−) or I(−)) INHIBIT and INHIBIT-OR combinatorial logic gates in water. More fluorescent natural products with intrinsic logic properties await to be discover...

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Detalles Bibliográficos
Autores principales: Agius, Nicola', Magri, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10153600/
https://www.ncbi.nlm.nih.gov/pubmed/37143912
http://dx.doi.org/10.1039/d3ra02704j
Descripción
Sumario:The fluorescent natural products, quinine, quinidine, cinchonine and cinchonidine are demonstrated as H(+)-enabled, halide-disabled (Cl(−), Br(−) or I(−)) INHIBIT and INHIBIT-OR combinatorial logic gates in water. More fluorescent natural products with intrinsic logic properties await to be discovered.