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Catenane formation of a cyclic poly(alkyl sorbate) via chain-growth polymerization induced by an N-heterocyclic carbene and ring-closing without extreme dilution

1,3-Di-tert-butylimidazol-2-ylidene (NHCtBu), a typical N-heterocyclic carbene (NHC), was previously found to induce the anionic chain-growth polymerization of ethyl sorbate (ES) in the presence of an aluminum Lewis acid, i.e., methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD), in which...

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Detalles Bibliográficos
Autores principales:	Yato, Hirotake, Oto, Kota, Takasu, Akinori, Higuchi, Masahiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155494/ https://www.ncbi.nlm.nih.gov/pubmed/37152560 http://dx.doi.org/10.1039/d3ra01614e

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