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A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole

Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. Th...

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Autores principales: Saleem, Qasar, Shahid, Sammia, Rahim, Abdur, Bajaber, Majed A., Mansoor, Sana, Javed, Mohsin, Iqbal, Shahid, Bahadur, Ali, Aljazzar, Samar O., Pashameah, Rami Adel, AlSubhi, Samah A., Alzahrani, Eman, Farouk, Abd-ElAziem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155604/
https://www.ncbi.nlm.nih.gov/pubmed/37152558
http://dx.doi.org/10.1039/d2ra07847c
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author Saleem, Qasar
Shahid, Sammia
Rahim, Abdur
Bajaber, Majed A.
Mansoor, Sana
Javed, Mohsin
Iqbal, Shahid
Bahadur, Ali
Aljazzar, Samar O.
Pashameah, Rami Adel
AlSubhi, Samah A.
Alzahrani, Eman
Farouk, Abd-ElAziem
author_facet Saleem, Qasar
Shahid, Sammia
Rahim, Abdur
Bajaber, Majed A.
Mansoor, Sana
Javed, Mohsin
Iqbal, Shahid
Bahadur, Ali
Aljazzar, Samar O.
Pashameah, Rami Adel
AlSubhi, Samah A.
Alzahrani, Eman
Farouk, Abd-ElAziem
author_sort Saleem, Qasar
collection PubMed
description Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 μA cm(−2)), LOD (1.52 × 10(−7) μM), LOQ (3.52 × 10(−5) μM), linear range (0.02–2500 μM), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation–reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme.
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spelling pubmed-101556042023-05-04 A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole Saleem, Qasar Shahid, Sammia Rahim, Abdur Bajaber, Majed A. Mansoor, Sana Javed, Mohsin Iqbal, Shahid Bahadur, Ali Aljazzar, Samar O. Pashameah, Rami Adel AlSubhi, Samah A. Alzahrani, Eman Farouk, Abd-ElAziem RSC Adv Chemistry Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 μA cm(−2)), LOD (1.52 × 10(−7) μM), LOQ (3.52 × 10(−5) μM), linear range (0.02–2500 μM), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation–reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme. The Royal Society of Chemistry 2023-05-03 /pmc/articles/PMC10155604/ /pubmed/37152558 http://dx.doi.org/10.1039/d2ra07847c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Saleem, Qasar
Shahid, Sammia
Rahim, Abdur
Bajaber, Majed A.
Mansoor, Sana
Javed, Mohsin
Iqbal, Shahid
Bahadur, Ali
Aljazzar, Samar O.
Pashameah, Rami Adel
AlSubhi, Samah A.
Alzahrani, Eman
Farouk, Abd-ElAziem
A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title_full A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title_fullStr A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title_full_unstemmed A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title_short A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
title_sort highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155604/
https://www.ncbi.nlm.nih.gov/pubmed/37152558
http://dx.doi.org/10.1039/d2ra07847c
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