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A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole
Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. Th...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155604/ https://www.ncbi.nlm.nih.gov/pubmed/37152558 http://dx.doi.org/10.1039/d2ra07847c |
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author | Saleem, Qasar Shahid, Sammia Rahim, Abdur Bajaber, Majed A. Mansoor, Sana Javed, Mohsin Iqbal, Shahid Bahadur, Ali Aljazzar, Samar O. Pashameah, Rami Adel AlSubhi, Samah A. Alzahrani, Eman Farouk, Abd-ElAziem |
author_facet | Saleem, Qasar Shahid, Sammia Rahim, Abdur Bajaber, Majed A. Mansoor, Sana Javed, Mohsin Iqbal, Shahid Bahadur, Ali Aljazzar, Samar O. Pashameah, Rami Adel AlSubhi, Samah A. Alzahrani, Eman Farouk, Abd-ElAziem |
author_sort | Saleem, Qasar |
collection | PubMed |
description | Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 μA cm(−2)), LOD (1.52 × 10(−7) μM), LOQ (3.52 × 10(−5) μM), linear range (0.02–2500 μM), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation–reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme. |
format | Online Article Text |
id | pubmed-10155604 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-101556042023-05-04 A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole Saleem, Qasar Shahid, Sammia Rahim, Abdur Bajaber, Majed A. Mansoor, Sana Javed, Mohsin Iqbal, Shahid Bahadur, Ali Aljazzar, Samar O. Pashameah, Rami Adel AlSubhi, Samah A. Alzahrani, Eman Farouk, Abd-ElAziem RSC Adv Chemistry Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 μA cm(−2)), LOD (1.52 × 10(−7) μM), LOQ (3.52 × 10(−5) μM), linear range (0.02–2500 μM), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation–reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme. The Royal Society of Chemistry 2023-05-03 /pmc/articles/PMC10155604/ /pubmed/37152558 http://dx.doi.org/10.1039/d2ra07847c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Saleem, Qasar Shahid, Sammia Rahim, Abdur Bajaber, Majed A. Mansoor, Sana Javed, Mohsin Iqbal, Shahid Bahadur, Ali Aljazzar, Samar O. Pashameah, Rami Adel AlSubhi, Samah A. Alzahrani, Eman Farouk, Abd-ElAziem A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title | A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title_full | A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title_fullStr | A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title_full_unstemmed | A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title_short | A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
title_sort | highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155604/ https://www.ncbi.nlm.nih.gov/pubmed/37152558 http://dx.doi.org/10.1039/d2ra07847c |
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