Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups

A synthetic route to the bench-stable fluorinated masked carbene reagent diethyl 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate, bearing a trifluoromethyl and a difluoromethyl group is reported for the first time. Its application in CuI-catalyzed cyclopropanation reactions with aromatic and aliphati...

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Detalles Bibliográficos
Autores principales: Hajdin, Ita, Pajkert, Romana, Keßler, Mira, Han, Jianlin, Mei, Haibo, Röschenthaler, Gerd-Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155617/
https://www.ncbi.nlm.nih.gov/pubmed/37153646
http://dx.doi.org/10.3762/bjoc.19.39

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155617/
https://www.ncbi.nlm.nih.gov/pubmed/37153646
http://dx.doi.org/10.3762/bjoc.19.39

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