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Visible-light-induced chemo-, diastereo- and enantioselective α-C(sp(3))–H functionalization of alkyl silanes

A catalytic asymmetric α-C(sp(3))–H functionalization of alkyl silanes with benzosultams was realized by merging photoredox and chiral Lewis acid catalysis. The key to success was the choice of photocatalyst with an appropriate redox potential and non-nucleophilic solvent, providing a novel entry to...

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Detalles Bibliográficos
Autores principales:	Feng, Lili, Chen, Xiaofan, Guo, Ning, Zhou, Yuqiao, Lin, Lili, Cao, Weidi, Feng, Xiaoming
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155911/ https://www.ncbi.nlm.nih.gov/pubmed/37152254 http://dx.doi.org/10.1039/d3sc00919j

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