Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles

We reduce di-n-butylmagnesium with arene (naphthalene, biphenyl, phenanthrene) radical anions and dianions to obtain metallic, plasmonic Mg nanoparticles. Their size and shape depends on the dianion concentration and reduction potential. Based on these results, we demonstrate a seeded growth Mg nano...

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Detalles Bibliográficos
Autores principales: Lomonosov, Vladimir, Hopper, Elizabeth R., Ringe, Emilie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10157803/
https://www.ncbi.nlm.nih.gov/pubmed/37078617
http://dx.doi.org/10.1039/d3cc00958k
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author Lomonosov, Vladimir
Hopper, Elizabeth R.
Ringe, Emilie
author_facet Lomonosov, Vladimir
Hopper, Elizabeth R.
Ringe, Emilie
author_sort Lomonosov, Vladimir
collection PubMed
description We reduce di-n-butylmagnesium with arene (naphthalene, biphenyl, phenanthrene) radical anions and dianions to obtain metallic, plasmonic Mg nanoparticles. Their size and shape depends on the dianion concentration and reduction potential. Based on these results, we demonstrate a seeded growth Mg nanoparticle synthesis and report homogeneous shapes with controllable monodisperse size distributions.
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spelling pubmed-101578032023-05-05 Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles Lomonosov, Vladimir Hopper, Elizabeth R. Ringe, Emilie Chem Commun (Camb) Chemistry We reduce di-n-butylmagnesium with arene (naphthalene, biphenyl, phenanthrene) radical anions and dianions to obtain metallic, plasmonic Mg nanoparticles. Their size and shape depends on the dianion concentration and reduction potential. Based on these results, we demonstrate a seeded growth Mg nanoparticle synthesis and report homogeneous shapes with controllable monodisperse size distributions. The Royal Society of Chemistry 2023-04-12 /pmc/articles/PMC10157803/ /pubmed/37078617 http://dx.doi.org/10.1039/d3cc00958k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Lomonosov, Vladimir
Hopper, Elizabeth R.
Ringe, Emilie
Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title_full Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title_fullStr Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title_full_unstemmed Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title_short Seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
title_sort seed-mediated synthesis of monodisperse plasmonic magnesium nanoparticles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10157803/
https://www.ncbi.nlm.nih.gov/pubmed/37078617
http://dx.doi.org/10.1039/d3cc00958k
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AT ringeemilie seedmediatedsynthesisofmonodisperseplasmonicmagnesiumnanoparticles

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