(N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)

The mol­ecule of the title compound, [Rh(C(13)H(10)NO(2)){As(C(6)H(5))(3)}(CO)] or [Rh(BPHA)(AsPh(3))(CO)] (BPHA is the N-benzoyl-N-phenyl­hydroxy­laminate anion), comprises a bidentate N-benzoyl-N-phenyl­hydroxy­laminate anion coordinating through the O atoms to the soft Lewis acid, rhodium(I), and...

Descripción completa

Detalles Bibliográficos
Autores principales: Motente, Mokete A., Venter, Johan, Brink, Alice
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162025/
https://www.ncbi.nlm.nih.gov/pubmed/37151208
http://dx.doi.org/10.1107/S2414314623003553
_version_ 1785037617394352128
author Motente, Mokete A.
Venter, Johan
Brink, Alice
author_facet Motente, Mokete A.
Venter, Johan
Brink, Alice
author_sort Motente, Mokete A.
collection PubMed
description The mol­ecule of the title compound, [Rh(C(13)H(10)NO(2)){As(C(6)H(5))(3)}(CO)] or [Rh(BPHA)(AsPh(3))(CO)] (BPHA is the N-benzoyl-N-phenyl­hydroxy­laminate anion), comprises a bidentate N-benzoyl-N-phenyl­hydroxy­laminate anion coordinating through the O atoms to the soft Lewis acid, rhodium(I), and two monodentate ligands, viz. tri­phenyl­arsine and carbonyl. The resulting CO(2)As coordination environment around the central Rh(I) atom is distorted square planar.= [Image: see text]
format Online
Article
Text
id pubmed-10162025
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-101620252023-05-06 (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I) Motente, Mokete A. Venter, Johan Brink, Alice IUCrdata Data Reports The mol­ecule of the title compound, [Rh(C(13)H(10)NO(2)){As(C(6)H(5))(3)}(CO)] or [Rh(BPHA)(AsPh(3))(CO)] (BPHA is the N-benzoyl-N-phenyl­hydroxy­laminate anion), comprises a bidentate N-benzoyl-N-phenyl­hydroxy­laminate anion coordinating through the O atoms to the soft Lewis acid, rhodium(I), and two monodentate ligands, viz. tri­phenyl­arsine and carbonyl. The resulting CO(2)As coordination environment around the central Rh(I) atom is distorted square planar.= [Image: see text] International Union of Crystallography 2023-04-25 /pmc/articles/PMC10162025/ /pubmed/37151208 http://dx.doi.org/10.1107/S2414314623003553 Text en © Motente et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Motente, Mokete A.
Venter, Johan
Brink, Alice
(N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title_full (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title_fullStr (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title_full_unstemmed (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title_short (N-Benzoyl-N-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(I)
title_sort (n-benzoyl-n-phenyl­hydroxy­laminato)carbon­yl(tri­phenyl­arsine)rhodium(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162025/
https://www.ncbi.nlm.nih.gov/pubmed/37151208
http://dx.doi.org/10.1107/S2414314623003553
work_keys_str_mv AT motentemoketea nbenzoylnphenylhydroxylaminatocarbonyltriphenylarsinerhodiumi
AT venterjohan nbenzoylnphenylhydroxylaminatocarbonyltriphenylarsinerhodiumi
AT brinkalice nbenzoylnphenylhydroxylaminatocarbonyltriphenylarsinerhodiumi

Ejemplares similares