9-(Pyrrolidinium-1-yl)-9-boranuidabi­cyclo­[3.3.1]nona­ne

The title compound, C(12)H(24)BN, is an adduct formed from 9-borabi­cyclo­[3.3.1]nonane (9-BBN) and pyrrolidine. It crystallizes in the triclinic space group P [Image: see text] with three mol­ecules in the asymmetric unit, one of which has disorder of the pyrrolidine ring. The B—N bond lengths are...

Descripción completa

Detalles Bibliográficos
Autores principales: Herbig, Marcus, Böhme, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162026/
https://www.ncbi.nlm.nih.gov/pubmed/37151199
http://dx.doi.org/10.1107/S2414314623003322
Descripción
Sumario:The title compound, C(12)H(24)BN, is an adduct formed from 9-borabi­cyclo­[3.3.1]nonane (9-BBN) and pyrrolidine. It crystallizes in the triclinic space group P [Image: see text] with three mol­ecules in the asymmetric unit, one of which has disorder of the pyrrolidine ring. The B—N bond lengths are between 1.631 (2) and 1.641 (2) Å. The boron and nitro­gen atoms are bound to one hydrogen atom each. These hydrogen atoms are in anti­periplanar orientation. Both six-membered rings of the 9-BBN unit are in a chair conformation in all three mol­ecules. Differences between the three crystallographic independent mol­ecules are found in the five-membered rings of the pyrrolidine unit. These adopt different twisted and envelope conformations. [Image: see text]

Ejemplares similares