Synthesis and crystal structure of catena-poly[[[aqua­{2-[(E)-(1-cyano-2-imino-2-meth­oxy­ethyl­idene)hydrazin­yl]benzene­sulfonato}­sodium]-di-μ-aqua] dihydrate]

In the polymeric title compound, {[Na(C(10)H(9)N(4)O(4)S)(H(2)O)(3)]·2H(2)O}( n ), sixfold coordinated Na(+) cations are linked into a chain parallel to [010] by sharing common water mol­ecules. Next to the four bridging water mol­ecules, each Na(+) cation of the chain is bonded to the O atom of a t...

Descripción completa

Detalles Bibliográficos
Autores principales: Aliyeva, Vusala A., Aliyeva, Fargana S., Akkurt, Mehmet, Yıldırım, Sema Öztürk, Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162073/
https://www.ncbi.nlm.nih.gov/pubmed/37151833
http://dx.doi.org/10.1107/S2056989023003602
Descripción
Sumario:In the polymeric title compound, {[Na(C(10)H(9)N(4)O(4)S)(H(2)O)(3)]·2H(2)O}( n ), sixfold coordinated Na(+) cations are linked into a chain parallel to [010] by sharing common water mol­ecules. Next to the four bridging water mol­ecules, each Na(+) cation of the chain is bonded to the O atom of a terminal water mol­ecule and an O atom of the SO(3) (−) group of the sulfonate anion. Classical O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds and additional π–π inter­actions connect these chains into a three-dimensional network.

Ejemplares similares