Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)

In the title complex, [Ni(C(14)H(15)N(2)O(2))(2)], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural cha...

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Autores principales: Khan, Sultana Shakila, Howlader, Md. Belayet Hossain, Sheikh, Md. Chanmiya, Miyatake, Ryuta, Zangrando, Ennio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162078/
https://www.ncbi.nlm.nih.gov/pubmed/37151832
http://dx.doi.org/10.1107/S2056989023002918
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author Khan, Sultana Shakila
Howlader, Md. Belayet Hossain
Sheikh, Md. Chanmiya
Miyatake, Ryuta
Zangrando, Ennio
author_facet Khan, Sultana Shakila
Howlader, Md. Belayet Hossain
Sheikh, Md. Chanmiya
Miyatake, Ryuta
Zangrando, Ennio
author_sort Khan, Sultana Shakila
collection PubMed
description In the title complex, [Ni(C(14)H(15)N(2)O(2))(2)], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole mol­ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)°. The crystal packing is supported by C—H⋯π and C—H⋯O inter­actions that form a di-periodic layered network.
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spelling pubmed-101620782023-05-06 Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II) Khan, Sultana Shakila Howlader, Md. Belayet Hossain Sheikh, Md. Chanmiya Miyatake, Ryuta Zangrando, Ennio Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [Ni(C(14)H(15)N(2)O(2))(2)], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole mol­ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)°. The crystal packing is supported by C—H⋯π and C—H⋯O inter­actions that form a di-periodic layered network. International Union of Crystallography 2023-04-14 /pmc/articles/PMC10162078/ /pubmed/37151832 http://dx.doi.org/10.1107/S2056989023002918 Text en © Khan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Khan, Sultana Shakila
Howlader, Md. Belayet Hossain
Sheikh, Md. Chanmiya
Miyatake, Ryuta
Zangrando, Ennio
Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title_full Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title_fullStr Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title_full_unstemmed Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title_short Crystal structure of bis­[4-(all­yloxy)-N′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(II)
title_sort crystal structure of bis­[4-(all­yloxy)-n′-(but-2-en-1-yl­idene)benzohydrazidato]nickel(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162078/
https://www.ncbi.nlm.nih.gov/pubmed/37151832
http://dx.doi.org/10.1107/S2056989023002918
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