Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]

The mol­ecular and crystal structure of the title binuclear Zn(2+) complex, [Zn(2)(C(8)H(13)O(3))(4)(C(2)H(5)OH)(2)], with enolated anionic tert-butyl­aceto­acetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octa­hedra formed by six oxygen atoms that belong to...

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Autores principales: Shtokvysh, Olherd O., Dyakonenko, Viktoriya V., Koval, Lyudmila I., Pekhnyo, Vasyl I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162079/
https://www.ncbi.nlm.nih.gov/pubmed/37151829
http://dx.doi.org/10.1107/S2056989023003377
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author Shtokvysh, Olherd O.
Dyakonenko, Viktoriya V.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
author_facet Shtokvysh, Olherd O.
Dyakonenko, Viktoriya V.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
author_sort Shtokvysh, Olherd O.
collection PubMed
description The mol­ecular and crystal structure of the title binuclear Zn(2+) complex, [Zn(2)(C(8)H(13)O(3))(4)(C(2)H(5)OH)(2)], with enolated anionic tert-butyl­aceto­acetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octa­hedra formed by six oxygen atoms that belong to three ligand mol­ecules and a coordinated ethanol mol­ecule. In the crystal phase, alternating layers can be distinguished parallel to the ac plane. A Hirshfeld surface analysis showed that there are no strong inter­molecular inter­actions in the structure. The most significant contributions to the overall crystal packing are from H⋯H inter­molecular contacts.
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spelling pubmed-101620792023-05-06 Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)] Shtokvysh, Olherd O. Dyakonenko, Viktoriya V. Koval, Lyudmila I. Pekhnyo, Vasyl I. Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular and crystal structure of the title binuclear Zn(2+) complex, [Zn(2)(C(8)H(13)O(3))(4)(C(2)H(5)OH)(2)], with enolated anionic tert-butyl­aceto­acetate and ethanol was analysed. The coordination polyhedra of the Zn atoms are distorted octa­hedra formed by six oxygen atoms that belong to three ligand mol­ecules and a coordinated ethanol mol­ecule. In the crystal phase, alternating layers can be distinguished parallel to the ac plane. A Hirshfeld surface analysis showed that there are no strong inter­molecular inter­actions in the structure. The most significant contributions to the overall crystal packing are from H⋯H inter­molecular contacts. International Union of Crystallography 2023-04-21 /pmc/articles/PMC10162079/ /pubmed/37151829 http://dx.doi.org/10.1107/S2056989023003377 Text en © Shtokvysh et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shtokvysh, Olherd O.
Dyakonenko, Viktoriya V.
Koval, Lyudmila I.
Pekhnyo, Vasyl I.
Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title_full Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title_fullStr Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title_short Crystal structure and Hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(II)]
title_sort crystal structure and hirshfeld surface analysis of bis­(μ-4-tert-but­oxy-4-oxobut-2-en-2-olato)bis­[(4-tert-but­oxy-4-oxobut-2-en-2-olato)ethano­lzinc(ii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162079/
https://www.ncbi.nlm.nih.gov/pubmed/37151829
http://dx.doi.org/10.1107/S2056989023003377
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