Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica

In the title compound, C(20)H(26)O(5), the two cyclo­hexane rings adopt boat and half-chair conformations. In the crystal, adjacent mol­ecules are connected by inter­molecular C—H⋯O hydrogen bonds, forming a three-dimensional network. According to a Hirshfeld surface study, H⋯H inter­actions are the...

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Autores principales: Karimli, Elvin G., Khrustalev, Victor N., Kurasova, Margarita N., Akkurt, Mehmet, Khalilov, Ali N., Bhattarai, Ajaya, Mamedov, İbrahim G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162084/
https://www.ncbi.nlm.nih.gov/pubmed/37151821
http://dx.doi.org/10.1107/S205698902300333X
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author Karimli, Elvin G.
Khrustalev, Victor N.
Kurasova, Margarita N.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
author_facet Karimli, Elvin G.
Khrustalev, Victor N.
Kurasova, Margarita N.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
author_sort Karimli, Elvin G.
collection PubMed
description In the title compound, C(20)H(26)O(5), the two cyclo­hexane rings adopt boat and half-chair conformations. In the crystal, adjacent mol­ecules are connected by inter­molecular C—H⋯O hydrogen bonds, forming a three-dimensional network. According to a Hirshfeld surface study, H⋯H inter­actions are the most significant contributors to the crystal packing (63.0%).
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spelling pubmed-101620842023-05-06 Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica Karimli, Elvin G. Khrustalev, Victor N. Kurasova, Margarita N. Akkurt, Mehmet Khalilov, Ali N. Bhattarai, Ajaya Mamedov, İbrahim G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(26)O(5), the two cyclo­hexane rings adopt boat and half-chair conformations. In the crystal, adjacent mol­ecules are connected by inter­molecular C—H⋯O hydrogen bonds, forming a three-dimensional network. According to a Hirshfeld surface study, H⋯H inter­actions are the most significant contributors to the crystal packing (63.0%). International Union of Crystallography 2023-04-21 /pmc/articles/PMC10162084/ /pubmed/37151821 http://dx.doi.org/10.1107/S205698902300333X Text en © Karimli et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Karimli, Elvin G.
Khrustalev, Victor N.
Kurasova, Margarita N.
Akkurt, Mehmet
Khalilov, Ali N.
Bhattarai, Ajaya
Mamedov, İbrahim G.
Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title_full Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title_fullStr Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title_short Crystal structure and Hirshfeld surface analysis of (5aS,8aR)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (Z)-2-methyl­but-2-enoate extracted from Ferula persica
title_sort crystal structure and hirshfeld surface analysis of (5as,8ar)-3,5a-dimethyl-8-methyl­idene-2-oxododeca­hydro­oxireno[2′,3′:6,7]naphtho­[1,2-b]furan-6-yl (z)-2-methyl­but-2-enoate extracted from ferula persica
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162084/
https://www.ncbi.nlm.nih.gov/pubmed/37151821
http://dx.doi.org/10.1107/S205698902300333X
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