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Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine
The title compound, C(23)H(15)BrN(2)OS, was the unexpected product in an attempted synthesis of the isomeric 3-(benzo[d]thiazol-2-yl)-6-bromo-1-p-tolylquinolin-2(1H)-one. The C(chromene)=N—C angle is wide [125.28 (8)°]. The benzothiazole and chromene ring systems are almost coplanar, with their...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162085/ https://www.ncbi.nlm.nih.gov/pubmed/37151827 http://dx.doi.org/10.1107/S2056989023002979 |
| _version_ | 1785037626714095616 |
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| author | Abdallah, Amira E. M. Elgemeie, Galal H. Jones, Peter G. |
| author_facet | Abdallah, Amira E. M. Elgemeie, Galal H. Jones, Peter G. |
| author_sort | Abdallah, Amira E. M. |
| collection | PubMed |
| description | The title compound, C(23)H(15)BrN(2)OS, was the unexpected product in an attempted synthesis of the isomeric 3-(benzo[d]thiazol-2-yl)-6-bromo-1-p-tolylquinolin-2(1H)-one. The C(chromene)=N—C angle is wide [125.28 (8)°]. The benzothiazole and chromene ring systems are almost coplanar, with their planes parallel to (1 [Image: see text] 0); the toluene ring system is rotated by ca 40° out of the chromene plane. The molecular packing involves layers with π-stacking, borderline ‘weak’ hydrogen bonds and possible C—H⋯π contacts. |
| format | Online Article Text |
| id | pubmed-10162085 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-101620852023-05-06 Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine Abdallah, Amira E. M. Elgemeie, Galal H. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(15)BrN(2)OS, was the unexpected product in an attempted synthesis of the isomeric 3-(benzo[d]thiazol-2-yl)-6-bromo-1-p-tolylquinolin-2(1H)-one. The C(chromene)=N—C angle is wide [125.28 (8)°]. The benzothiazole and chromene ring systems are almost coplanar, with their planes parallel to (1 [Image: see text] 0); the toluene ring system is rotated by ca 40° out of the chromene plane. The molecular packing involves layers with π-stacking, borderline ‘weak’ hydrogen bonds and possible C—H⋯π contacts. International Union of Crystallography 2023-04-14 /pmc/articles/PMC10162085/ /pubmed/37151827 http://dx.doi.org/10.1107/S2056989023002979 Text en © Abdallah et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Abdallah, Amira E. M. Elgemeie, Galal H. Jones, Peter G. Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title | Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title_full | Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title_fullStr | Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title_full_unstemmed | Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title_short | Crystal structure of N-[3-(benzo[d]thiazol-2-yl)-6-bromo-2H-chromen-2-ylidene]-4-methylbenzenamine |
| title_sort | crystal structure of n-[3-(benzo[d]thiazol-2-yl)-6-bromo-2h-chromen-2-ylidene]-4-methylbenzenamine |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162085/ https://www.ncbi.nlm.nih.gov/pubmed/37151827 http://dx.doi.org/10.1107/S2056989023002979 |
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