Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system

A simple and metal-free catalytic system composed of NaO(t)Bu/DMF and an O(2) balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfa...

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Detalles Bibliográficos
Autores principales: Wang, Xue, Guo, Xinyuan, Wang, Xinmei, Li, Chi, Wang, Shanjun, Li, Han, Gao, Yan’an, Li, Yiying, Wang, Jinhui, Xu, Huanjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10170353/
https://www.ncbi.nlm.nih.gov/pubmed/37181510
http://dx.doi.org/10.1039/d3ra01104f
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author Wang, Xue
Guo, Xinyuan
Wang, Xinmei
Li, Chi
Wang, Shanjun
Li, Han
Gao, Yan’an
Li, Yiying
Wang, Jinhui
Xu, Huanjun
author_facet Wang, Xue
Guo, Xinyuan
Wang, Xinmei
Li, Chi
Wang, Shanjun
Li, Han
Gao, Yan’an
Li, Yiying
Wang, Jinhui
Xu, Huanjun
author_sort Wang, Xue
collection PubMed
description A simple and metal-free catalytic system composed of NaO(t)Bu/DMF and an O(2) balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfactory to excellent yield by this catalytic system.
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spelling pubmed-101703532023-05-11 Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system Wang, Xue Guo, Xinyuan Wang, Xinmei Li, Chi Wang, Shanjun Li, Han Gao, Yan’an Li, Yiying Wang, Jinhui Xu, Huanjun RSC Adv Chemistry A simple and metal-free catalytic system composed of NaO(t)Bu/DMF and an O(2) balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfactory to excellent yield by this catalytic system. The Royal Society of Chemistry 2023-05-10 /pmc/articles/PMC10170353/ /pubmed/37181510 http://dx.doi.org/10.1039/d3ra01104f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Wang, Xue
Guo, Xinyuan
Wang, Xinmei
Li, Chi
Wang, Shanjun
Li, Han
Gao, Yan’an
Li, Yiying
Wang, Jinhui
Xu, Huanjun
Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title_full Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title_fullStr Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title_full_unstemmed Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title_short Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
title_sort conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10170353/
https://www.ncbi.nlm.nih.gov/pubmed/37181510
http://dx.doi.org/10.1039/d3ra01104f
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