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Isopropenyl phosphate as an atom efficient reagent for phosphorylation of alcohols with catalytic base
The atom efficient transesterification of phosphate esters with catalytic base was investigated using an isopropenyl leaving group, generating acetone as the only by-product. The reaction proceeds in good yields at room temperature, with excellent chemoselectivity towards primary alcohols. Mechanist...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10170494/ https://www.ncbi.nlm.nih.gov/pubmed/37180006 http://dx.doi.org/10.1039/d3ra02293e |