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Enantioselective catalytic remote perfluoroalkylation of α-branched enals driven by light

Herein, we report a photochemical organocatalytic method for the asymmetric introduction of perfluoroalkyl fragments (including the valuable trifluoromethyl moiety) at the remote γ-position of α-branched enals. The chemistry exploits the ability of extended enamines (dienamines) to form photoactive...

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Detalles Bibliográficos
Autores principales:	Balletti, Matteo, Wachsmuth, Tommy, Di Sabato, Antonio, Hartley, Will C., Melchiorre, Paolo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171066/ https://www.ncbi.nlm.nih.gov/pubmed/37181764 http://dx.doi.org/10.1039/d3sc01347b

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