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Palladium-catalysed enantio- and regioselective (3 + 2) cycloaddition reactions of sulfamidate imine-derived 1-azadienes towards spirocyclic cyclopentanes

An enantio- and diastereoselective Pd-catalysed (3 + 2) cycloaddition of bis(trifluoroethyl) 2-vinyl-cyclopropane-1,1-dicarboxylate (VCP) with cyclic sulfamidate imine-derived 1-azadienes (SDAs) has been developed. These reactions provide highly functionalized spiroheterocycles having three contiguo...

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Detalles Bibliográficos
Autores principales:	Pham, Quoc Hoang, Tague, Andrew J., Richardson, Christopher, Gardiner, Michael G., Pyne, Stephen G., Hyland, Christopher J. T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171190/ https://www.ncbi.nlm.nih.gov/pubmed/37181759 http://dx.doi.org/10.1039/d3sc01510f

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