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Stereoselective synthesis of (E)-α,β-unsaturated esters: triethylamine-catalyzed allylic rearrangement of enol phosphates

α,β-Unsaturated esters are key structural motifs widely distributed in various biologically active molecules, and their Z/E-stereoselective synthesis has always been considered highly attractive in organic synthesis. Herein, we present a >99% (E)-stereoselective one-pot synthetic approach towards...

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Detalles Bibliográficos
Autores principales: Zhang, Yulong, Guo, Huichuang, Wu, Qian, Bi, Xiaojing, Shi, Enxue, Xiao, Junhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10173029/
https://www.ncbi.nlm.nih.gov/pubmed/37181505
http://dx.doi.org/10.1039/d3ra02430j

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