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Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology

[Image: see text] To eliminate internal defects of grains developed during melt-cast charging, the formation mechanism and the trend of crystal morphology of internal defects of 2,4,6-trinitrotoluene and 2,4-dinitroanisole-based melt-cast explosives under different process conditions were simulated....

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Autores principales: Wang, Su-Wei, Zhang, Yu-Long, Wu, Chao, Xiao, Lei, Lin, Gao-Ming, Hu, Yu-Bing, Hao, Ga-Zi, Guo, Hu, Zhang, Guang-Pu, Jiang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10173312/
https://www.ncbi.nlm.nih.gov/pubmed/37179598
http://dx.doi.org/10.1021/acsomega.3c00709
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author Wang, Su-Wei
Zhang, Yu-Long
Wu, Chao
Xiao, Lei
Lin, Gao-Ming
Hu, Yu-Bing
Hao, Ga-Zi
Guo, Hu
Zhang, Guang-Pu
Jiang, Wei
author_facet Wang, Su-Wei
Zhang, Yu-Long
Wu, Chao
Xiao, Lei
Lin, Gao-Ming
Hu, Yu-Bing
Hao, Ga-Zi
Guo, Hu
Zhang, Guang-Pu
Jiang, Wei
author_sort Wang, Su-Wei
collection PubMed
description [Image: see text] To eliminate internal defects of grains developed during melt-cast charging, the formation mechanism and the trend of crystal morphology of internal defects of 2,4,6-trinitrotoluene and 2,4-dinitroanisole-based melt-cast explosives under different process conditions were simulated. The effects of solidification treatment on melt-cast explosive molding quality were investigated by combining pressurized feeding, head insulation, and water bath cooling. The single pressurized treatment technology results showed that grains were exposed to layer-by-layer solidification from outside to inside, resulting in V-shaped shrink areas of the contract cavity in the core. The defect area was proportional to the treatment temperature. However, the combination of treatment technologies, such as head insulation and water bath cooling, promoted longitudinal gradient solidification of the explosive and controllable migration of its internal defects. Moreover, the combined treatment technologies effectively improved the heat transfer efficiency of the explosive with the help of a water bath to reduce the solidification time, thus achieving highly efficient equal-material manufacturing of microdefect or zero-defect grains.
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spelling pubmed-101733122023-05-12 Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology Wang, Su-Wei Zhang, Yu-Long Wu, Chao Xiao, Lei Lin, Gao-Ming Hu, Yu-Bing Hao, Ga-Zi Guo, Hu Zhang, Guang-Pu Jiang, Wei ACS Omega [Image: see text] To eliminate internal defects of grains developed during melt-cast charging, the formation mechanism and the trend of crystal morphology of internal defects of 2,4,6-trinitrotoluene and 2,4-dinitroanisole-based melt-cast explosives under different process conditions were simulated. The effects of solidification treatment on melt-cast explosive molding quality were investigated by combining pressurized feeding, head insulation, and water bath cooling. The single pressurized treatment technology results showed that grains were exposed to layer-by-layer solidification from outside to inside, resulting in V-shaped shrink areas of the contract cavity in the core. The defect area was proportional to the treatment temperature. However, the combination of treatment technologies, such as head insulation and water bath cooling, promoted longitudinal gradient solidification of the explosive and controllable migration of its internal defects. Moreover, the combined treatment technologies effectively improved the heat transfer efficiency of the explosive with the help of a water bath to reduce the solidification time, thus achieving highly efficient equal-material manufacturing of microdefect or zero-defect grains. American Chemical Society 2023-04-25 /pmc/articles/PMC10173312/ /pubmed/37179598 http://dx.doi.org/10.1021/acsomega.3c00709 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Wang, Su-Wei
Zhang, Yu-Long
Wu, Chao
Xiao, Lei
Lin, Gao-Ming
Hu, Yu-Bing
Hao, Ga-Zi
Guo, Hu
Zhang, Guang-Pu
Jiang, Wei
Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title_full Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title_fullStr Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title_full_unstemmed Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title_short Equal-Material Manufacturing of a Thermoplastic Melt-Cast Explosive Using Thermal-Pressure Coupling Solidification Treatment Technology
title_sort equal-material manufacturing of a thermoplastic melt-cast explosive using thermal-pressure coupling solidification treatment technology
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10173312/
https://www.ncbi.nlm.nih.gov/pubmed/37179598
http://dx.doi.org/10.1021/acsomega.3c00709
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