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Copper(ii) defect-cubane water oxidation electrocatalysts: from molecular tetramers to oxidic nanostructures
We report on the synthesis and spectroscopic evidence for a sequence of structural transformations of a new defect-cubane type copper complex, [Cu(4)(pyalk)(4)(OAc)(4)](ClO(4))(HNEt(3)), which acts as a pre-catalyst for water oxidation. In situ and post-catalytic studies showed that the tetrameric c...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10174076/ https://www.ncbi.nlm.nih.gov/pubmed/37089062 http://dx.doi.org/10.1039/d3cc01005h |