Fe(3)O(4)@SiO(2)@KIT-6@2-ATP@Cu(I) as a catalyst for hydration of benzonitriles and reduction of nitroarenes

In this paper, a new type of magnetic mesoporous material (Fe(3)O(4)@SiO(2)@KIT-6@2-ATP@Cu(I)) was designed and synthesized and its application in the synthesis of amides and anilines was investigated. The structure of Fe(3)O(4)@SiO(2)@KIT-6@2-ATP@Cu(I) was characterized and identified using FTIR, S...

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Detalles Bibliográficos
Autores principales: Moradi, Zahra, Ghorbani-Choghamarani, Arash
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10175259/
https://www.ncbi.nlm.nih.gov/pubmed/37169905
http://dx.doi.org/10.1038/s41598-023-34409-z
Descripción
Sumario:In this paper, a new type of magnetic mesoporous material (Fe(3)O(4)@SiO(2)@KIT-6@2-ATP@Cu(I)) was designed and synthesized and its application in the synthesis of amides and anilines was investigated. The structure of Fe(3)O(4)@SiO(2)@KIT-6@2-ATP@Cu(I) was characterized and identified using FTIR, SEM, XRD, TGA, BET, VSM, and ICP techniques. An external magnet can easily remove the synthesized catalyst from the reaction medium, and be reused in several consequence runs.

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