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Open-[60]fullerene–aniline conjugates with near-infrared absorption
Two open-[60]fullerene–aniline conjugates were synthesized, in which the two-fold addition of diamine gave a thiazolidine-2-thione ring on the [60]fullerene cage in the presence of CS(2). By increasing the number of N,N-dimethylaniline moieties, the absorption edge was considerably shifted up to 120...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10177950/ https://www.ncbi.nlm.nih.gov/pubmed/37188248 http://dx.doi.org/10.1039/d3ra02113k |
Sumario: | Two open-[60]fullerene–aniline conjugates were synthesized, in which the two-fold addition of diamine gave a thiazolidine-2-thione ring on the [60]fullerene cage in the presence of CS(2). By increasing the number of N,N-dimethylaniline moieties, the absorption edge was considerably shifted up to 1200 nm owing to effective acceptor–donor interactions. |
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