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Synthesis and Structural Characterization of p-Carboranylamidine Derivatives †

In this contribution, the first amidinate and amidine derivatives of p-carborane are described. Double lithiation of p-carborane (1) with n-butyllithium followed by treatment with 1,3-diorganocarbodiimides, R–N=C=N–R (R = (i)Pr, Cy (= cyclohexyl)), in DME or THF afforded the new p-carboranylamidinat...

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Detalles Bibliográficos
Autores principales: Harmgarth, Nicole, Liebing, Phil, Lorenz, Volker, Engelhardt, Felix, Hilfert, Liane, Busse, Sabine, Goldhahn, Rüdiger, Edelmann, Frank T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179778/
https://www.ncbi.nlm.nih.gov/pubmed/37175246
http://dx.doi.org/10.3390/molecules28093837

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