Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands

In this paper, two benzimidazole derivative ligands were obtained using o-phenylenediamine and n-pyridine formaldehyde (n = 3, 4) by amine–aldol condensation reactions, which were reacted with selected inorganic metal salts by ambient temperature volatilization method to give compounds 1–4: {[(L1)(6...

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Detalles Bibliográficos
Autores principales: Ren, Chenfei, Li, Jian, Zhang, Xingxing, Niu, Yunyin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179940/
https://www.ncbi.nlm.nih.gov/pubmed/37175251
http://dx.doi.org/10.3390/molecules28093841
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author Ren, Chenfei
Li, Jian
Zhang, Xingxing
Niu, Yunyin
author_facet Ren, Chenfei
Li, Jian
Zhang, Xingxing
Niu, Yunyin
author_sort Ren, Chenfei
collection PubMed
description In this paper, two benzimidazole derivative ligands were obtained using o-phenylenediamine and n-pyridine formaldehyde (n = 3, 4) by amine–aldol condensation reactions, which were reacted with selected inorganic metal salts by ambient temperature volatilization method to give compounds 1–4: {[(L1)(6)]·[Cu(8)I(8)]} (1), {[L1]·[CuBr]·H(2)O} (2), {[L2]·[CuBr]}(n) (3), and {[(L2)(4)]·[Cu(4)I(4)]} (4). They were characterized by IR, UV-Vis absorption spectroscopy, thermogravimetric analysis, and single crystal X-ray analysis. Simultaneously, compounds 1–4 were found to possess photocatalytic degradation of ciprofloxacin (CIP) by preliminary experimental investigations.
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spelling pubmed-101799402023-05-13 Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands Ren, Chenfei Li, Jian Zhang, Xingxing Niu, Yunyin Molecules Article In this paper, two benzimidazole derivative ligands were obtained using o-phenylenediamine and n-pyridine formaldehyde (n = 3, 4) by amine–aldol condensation reactions, which were reacted with selected inorganic metal salts by ambient temperature volatilization method to give compounds 1–4: {[(L1)(6)]·[Cu(8)I(8)]} (1), {[L1]·[CuBr]·H(2)O} (2), {[L2]·[CuBr]}(n) (3), and {[(L2)(4)]·[Cu(4)I(4)]} (4). They were characterized by IR, UV-Vis absorption spectroscopy, thermogravimetric analysis, and single crystal X-ray analysis. Simultaneously, compounds 1–4 were found to possess photocatalytic degradation of ciprofloxacin (CIP) by preliminary experimental investigations. MDPI 2023-05-01 /pmc/articles/PMC10179940/ /pubmed/37175251 http://dx.doi.org/10.3390/molecules28093841 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ren, Chenfei
Li, Jian
Zhang, Xingxing
Niu, Yunyin
Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title_full Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title_fullStr Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title_full_unstemmed Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title_short Synthesis and Photocatalytic Properties of Four Coordination Compounds Constructed from Two Benzimidazole-Based Asymmetric Polyazocyclic Ligands
title_sort synthesis and photocatalytic properties of four coordination compounds constructed from two benzimidazole-based asymmetric polyazocyclic ligands
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179940/
https://www.ncbi.nlm.nih.gov/pubmed/37175251
http://dx.doi.org/10.3390/molecules28093841
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AT zhangxingxing synthesisandphotocatalyticpropertiesoffourcoordinationcompoundsconstructedfromtwobenzimidazolebasedasymmetricpolyazocyclicligands
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