Cargando…

DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy

The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersatur...

Descripción completa

Detalles Bibliográficos
Autores principales: Henle, Ramona, Dölling, Julia, Prahl, Ulrich, Nandi, Gerrit, Zilly, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179944/
https://www.ncbi.nlm.nih.gov/pubmed/37176345
http://dx.doi.org/10.3390/ma16093462
_version_ 1785041217892909056
author Henle, Ramona
Dölling, Julia
Prahl, Ulrich
Nandi, Gerrit
Zilly, Andreas
author_facet Henle, Ramona
Dölling, Julia
Prahl, Ulrich
Nandi, Gerrit
Zilly, Andreas
author_sort Henle, Ramona
collection PubMed
description The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersaturated specimens were tested in non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold rolling significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties.
format Online
Article
Text
id pubmed-10179944
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-101799442023-05-13 DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy Henle, Ramona Dölling, Julia Prahl, Ulrich Nandi, Gerrit Zilly, Andreas Materials (Basel) Article The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersaturated specimens were tested in non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold rolling significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties. MDPI 2023-04-29 /pmc/articles/PMC10179944/ /pubmed/37176345 http://dx.doi.org/10.3390/ma16093462 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Henle, Ramona
Dölling, Julia
Prahl, Ulrich
Nandi, Gerrit
Zilly, Andreas
DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title_full DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title_fullStr DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title_full_unstemmed DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title_short DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
title_sort dsc analysis of the effect of cold deformation on the precipitation kinetics of a binary cu-sc alloy
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179944/
https://www.ncbi.nlm.nih.gov/pubmed/37176345
http://dx.doi.org/10.3390/ma16093462
work_keys_str_mv AT henleramona dscanalysisoftheeffectofcolddeformationontheprecipitationkineticsofabinarycuscalloy
AT dollingjulia dscanalysisoftheeffectofcolddeformationontheprecipitationkineticsofabinarycuscalloy
AT prahlulrich dscanalysisoftheeffectofcolddeformationontheprecipitationkineticsofabinarycuscalloy
AT nandigerrit dscanalysisoftheeffectofcolddeformationontheprecipitationkineticsofabinarycuscalloy
AT zillyandreas dscanalysisoftheeffectofcolddeformationontheprecipitationkineticsofabinarycuscalloy