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DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy
The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersatur...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179944/ https://www.ncbi.nlm.nih.gov/pubmed/37176345 http://dx.doi.org/10.3390/ma16093462 |
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author | Henle, Ramona Dölling, Julia Prahl, Ulrich Nandi, Gerrit Zilly, Andreas |
author_facet | Henle, Ramona Dölling, Julia Prahl, Ulrich Nandi, Gerrit Zilly, Andreas |
author_sort | Henle, Ramona |
collection | PubMed |
description | The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersaturated specimens were tested in non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold rolling significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties. |
format | Online Article Text |
id | pubmed-10179944 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-101799442023-05-13 DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy Henle, Ramona Dölling, Julia Prahl, Ulrich Nandi, Gerrit Zilly, Andreas Materials (Basel) Article The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersaturated specimens were tested in non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold rolling significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties. MDPI 2023-04-29 /pmc/articles/PMC10179944/ /pubmed/37176345 http://dx.doi.org/10.3390/ma16093462 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Henle, Ramona Dölling, Julia Prahl, Ulrich Nandi, Gerrit Zilly, Andreas DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title | DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title_full | DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title_fullStr | DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title_full_unstemmed | DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title_short | DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy |
title_sort | dsc analysis of the effect of cold deformation on the precipitation kinetics of a binary cu-sc alloy |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10179944/ https://www.ncbi.nlm.nih.gov/pubmed/37176345 http://dx.doi.org/10.3390/ma16093462 |
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