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Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals

By utilizing low-grade bauxite desilication solution as raw material and adding lime after thermal reaction, adsorbent MCS was synthesized. X-ray diffraction, Brunauer–Emmett–Teller, Fourier transform infrared spectroscopy, and scanning electron microscopy were used to characterize the MCS, MCS-Pb,...

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Detalles Bibliográficos
Autores principales: Chen, Cheng, Chen, Chaoyi, Li, Junqi, Wang, Gangan, Lin, Xin, Ning, Deyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10180427/
https://www.ncbi.nlm.nih.gov/pubmed/37176388
http://dx.doi.org/10.3390/ma16093506
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author Chen, Cheng
Chen, Chaoyi
Li, Junqi
Wang, Gangan
Lin, Xin
Ning, Deyang
author_facet Chen, Cheng
Chen, Chaoyi
Li, Junqi
Wang, Gangan
Lin, Xin
Ning, Deyang
author_sort Chen, Cheng
collection PubMed
description By utilizing low-grade bauxite desilication solution as raw material and adding lime after thermal reaction, adsorbent MCS was synthesized. X-ray diffraction, Brunauer–Emmett–Teller, Fourier transform infrared spectroscopy, and scanning electron microscopy were used to characterize the MCS, MCS-Pb, and MCS-Cu. The Freundlich model was found to be more suitable for isothermal adsorption, suggesting that the adsorption of Cu(2+) and Pb(2+) by MCS is not limited to monolayer adsorption. According to the results of the experiment, the maximum adsorption capacities of lead ion and copper ion were found to be Pb(2+) (1921.506 mg/g) > Cu(2+) (561.885 mg/g), and the adsorption was controlled by chemical reactions following pseudo-second-order kinetics. Electrolyte study results indicated that the presence of background electrolyte did not affect the adsorption of Cu(2+) and Pb(2+) by MCS.
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spelling pubmed-101804272023-05-13 Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals Chen, Cheng Chen, Chaoyi Li, Junqi Wang, Gangan Lin, Xin Ning, Deyang Materials (Basel) Article By utilizing low-grade bauxite desilication solution as raw material and adding lime after thermal reaction, adsorbent MCS was synthesized. X-ray diffraction, Brunauer–Emmett–Teller, Fourier transform infrared spectroscopy, and scanning electron microscopy were used to characterize the MCS, MCS-Pb, and MCS-Cu. The Freundlich model was found to be more suitable for isothermal adsorption, suggesting that the adsorption of Cu(2+) and Pb(2+) by MCS is not limited to monolayer adsorption. According to the results of the experiment, the maximum adsorption capacities of lead ion and copper ion were found to be Pb(2+) (1921.506 mg/g) > Cu(2+) (561.885 mg/g), and the adsorption was controlled by chemical reactions following pseudo-second-order kinetics. Electrolyte study results indicated that the presence of background electrolyte did not affect the adsorption of Cu(2+) and Pb(2+) by MCS. MDPI 2023-05-02 /pmc/articles/PMC10180427/ /pubmed/37176388 http://dx.doi.org/10.3390/ma16093506 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chen, Cheng
Chen, Chaoyi
Li, Junqi
Wang, Gangan
Lin, Xin
Ning, Deyang
Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title_full Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title_fullStr Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title_full_unstemmed Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title_short Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals
title_sort preparation of mcs from low-grade bauxite desilication lye and adsorption of heavy metals
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10180427/
https://www.ncbi.nlm.nih.gov/pubmed/37176388
http://dx.doi.org/10.3390/ma16093506
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